NDLI: Synthesis, Characterization and Crystal Structures of Four Coordination Polymers

Content Provider	Springer Nature Link
Author	Awaleh, Mohamed Osman Hoch, Farhan Bouraleh Farah, Idriss Guirreh
Copyright Year	2013
Abstract	The bis(methylthio)methane building block was combined with AgX salt where X are weakly or noncoordinating counteranions (X = CF$_{3}$SO$_{3}$ $^{−}$ (1), PF$_{6}$ $^{−}$ (2), SbF$_{6}$ $^{−}$ (3) and BF$_{4}$ $^{−}$ (4)) in order to form cationic metal–organic frameworks where the anions only counterbalance the charge of the networks. The crystallographic data of those complexes are: (1) Monoclinic C2; a = 17.3226(2) Å; b = 9.2820(1) Å; c = 29.726(3) Å; β = 93.726(1)°; V = 4787.59(9) Å$^{3}$; Z = 4. (2) Monoclinic C2/c; a = 8.2468(4) Å; b = 19.101(1) Å; c = 10.1381(5) Å; β = 107.065(2)°; V = 1526.7(1) Å$^{3}$; Z = 4. (3) Monoclinic C2/c; a = 13.2985(4) Å; b = 16.1208(4) Å; c = 8.9804(3) Å; β = 95.883(2)°; V = 1915.1(1) Å$^{3}$; Z = 4. (4) Monoclinic C2/c; a = 16.7916(9) Å; b = 9.1090(4) Å; c = 22.670(1) Å; β = 99.676(4)°; V = 3418.2(3) Å$^{3}$; Z = 4. The coordination polymer 1 forms channel-like 3D-cationic framework in which the trifluoromethanesulfonate anions are located. The octahedral counteranions, PF$_{6}$ $^{−}$ (2) and SbF$_{6}$ $^{−}$ (3), allow the formation of similar cationic cross-linked one-dimensional coordination polymers. Coordination polymers 2 and 3 have hexagonal packing. The tetrahedral counteranion BF$_{4}$ $^{−}$ (4) gives rise to cationic layer-like coordination network where the tetrafluoroborate anions are inserted between those sheets.Four new silver(I)—coordination polymers have been obtained from the combination of bis(methylthio)methane building block and AgX salt where X are weakly or noncoordinating counteranions (X = CF$_{3}$SO$_{3}$ $^{−}$ (1), PF$_{6}$ $^{−}$ (2), SbF$_{6}$ $^{−}$ (3) and BF$_{4}$ $^{−}$ (4)). Those metallosupramolecular compounds have been characterized by elemental analysis, NMR spectroscopy, IR spectroscopy and X-ray crystallography.
Starting Page	685
Ending Page	693
Page Count	9
File Format	PDF
ISSN	10741542
Journal	Journal of Chemical Crystallography
Volume Number	43
Issue Number	12
e-ISSN	15728854
Language	English
Publisher	Springer US
Publisher Date	2013-09-28
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Coordination polymer X-ray diffraction Cationic metal organic framework Organometallic Chemistry Crystallography Physical Chemistry Inorganic Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics

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