NDLI: Supramolecular Cobalt(II), Copper(II) and Cadmium(II) Complexes Obtained from a Proton Transfer Compound including Pyridine-2,6-dicarboxylate and Propane-1,3-diaminium Ions; Synthesis, Characterization and Crystal Structure

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Supramolecular Cobalt(II), Copper(II) and Cadmium(II) Complexes Obtained from a Proton Transfer Compound including Pyridine-2,6-dicarboxylate and Propane-1,3-diaminium Ions; Synthesis, Characterization and Crystal Structure

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Supramolecular Cobalt(II), Copper(II) and Cadmium(II) Complexes Obtained from a Proton Transfer Compound including Pyridine-2,6-dicarboxylate and Propane-1,3-diaminium Ions; Synthesis, Characterization and Crystal Structure

Content Provider	Springer Nature Link
Author	Aghabozorg, Hossein Ghadermazi, Mohammad Nakhjavan, Bahar Manteghi, Faranak
Copyright Year	2007
Abstract	The three complexes (pnH$_{2}$)[Co(pydc)$_{2}$]·4H$_{2}$O 1, (pnH$_{2}$)[Cu(pydc)$_{2}$]·4H$_{2}$O 2, and (pnH$_{2}$)[Cd(pydc)$_{2}$]·3.5H$_{2}$O 3 (pn: propane-1,3-diamine, pydc: pyridine-2,6-dicarboxylate) were prepared using a proton transfer compound (pnH$_{2}$)(pydc)·(pydcH$_{2}$)·2.5H$_{2}$O, LH $_{ 2 }$ and corresponding metallic salts. The characterization was carried out using elemental analysis, IR and NMR spectroscopy, and single crystal X-ray diffraction. Complexes 1 and 2 crystallize in space group P $$ \bar 1 $$ , but complex 3 crystallizes in space group P2/c. Cell parameters of the complexes are a = 8.449(1) Å, b = 11.668(1) Å, c = 12.801(1) Å, α = 115.748(2)°, β = 93.038(2)°, γ = 97.867(2)° for 1; a = 7.973(2) Å, b = 16.632(2) Å, c = 25.280(5) Å, α = 94.178(6)°, β = 95.186(6)°, γ = 91.603(5)° for 2 and a = 20.055(1) Å, b = 13.8161(9) Å, c = 8.2418(5) Å, β = 100.086(1)° for 3. The three crystal structures illustrate that the metal ion is six-coordinated by two pydc’s. In structures of 2 and 3, it can be seen that propane-1,3-diaminium fragments have different conformations. The complexes have ion-pairing interactions, O–H···O, N–H···O and C–H···O hydrogen bonds, π–π stacking as well as van der Waals forces as the main factors in formation of their supramolecular structures. Supramolecular Cobalt(II), Copper(II) and Cadmium(II) Complexes Obtained from a Proton Transfer Compound including Pyridine-2,6-dicarboxylate and Propane-1,3-diaminium Ions; Synthesis, Characterization and Crystal Structure Hossein Aghabozorg, Mohammad Ghadermazi,Bahar Nakhjavan, Faranak ManteghiThe synthesis, characterization, crystal structure and non-covalent interactions of three supramolecular complexes of Co(II), Cu(II) and Cd(II) obtained by the reaction of a proton transfer compound i.e. (pnH$_{2}$)(pydc)·(pydcH$_{2}$)·2.5H$_{2}$O with the corresponding metallic salts are reported.
Starting Page	135
Ending Page	145
Page Count	11
File Format	PDF
ISSN	10741542
Journal	Journal of Chemical Crystallography
Volume Number	38
Issue Number	2
e-ISSN	15728854
Language	English
Publisher	Springer US
Publisher Date	2007-11-06
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Cobalt Copper Cadmium Pyridine-2,6-dicarboxylic acid Propane-1,3-diamine Crystal structure Inorganic Chemistry Physical Chemistry Crystallography Organometallic Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics

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