NDLI: Crystal and Molecular Structure of the 1:2 Adduct Formed Between N,N′-Butylenebis(imidazole) and Carboxylic Acid Derivatives

Content Provider	Springer Nature Link
Author	Jin, Shouwen Zhang, Wenbiao Wang, Daqi Gao, Hongfang Zhou, Jian Zhong Chen, Rongpo Xu, Xiaolei
Copyright Year	2009
Abstract	Two imidazolyl derived complexes [N,N′-butylenebis(imidazole): (fumaric acid)$_{2}$ (1), and N,N′-butylenebis(imidazole): (2,4,6-trinitrophenol)$_{2}$ (2)] were prepared and structurally characterized by X-ray crystallography. Compound 1 crystallizes in the triclinic, space group P−1, with a = 5.9990(12) Å, b = 8.1772(16) Å, c = 10.419(2) Å, α = 86.88(2)°, β = 84.73(3)°, γ = 77.03(4)°, V = 495.67(17) Å$^{3}$, Z = 1. For 1, two dimensional network structure is formed through imidazolium moieties forming hydrogen bonds to di-ionic carboxylate groups of fumarate chains. In the same network layers and adjacent layers, C–H···O contact also accompanies the N$^{+}$–H···O$^{−}$ hydrogen bonds, all these lead the extended architecture to show a three-dimensional lamellar structure. Compound 2 crystallizes in the triclinic, space group P − 1, with a = 7.0236(14) Å, b = 8.2831(17) Å, c = 12.053(2) Å, α = 106.05(4)°, β = 99.13(2)°, γ = 98.84(3)°, V = 650.8(2) Å$^{3}$, Z = 1. In 2, two parallel imidazolium cations and two antiparallel 2,4,6-trinitrophenolate anions formed 32-membered rings through hydrogen bonding interaction, these rings extended along the c axis direction to form one dimensional railway structure. Adjacent parallel railways connect further through C–H···O hydrogen bonds between the 2-CH of the imidazole ring and the NO$_{2}$ group O atoms. These weak interactions combined, the complex showed 3D layer structure.Two imidazolyl derived complexes [N,N′-butylenebis(imidazole): (fumaric acid)$_{2}$ (1), and N,N′-butylenebis(imidazole): (2,4,6-trinitrophenol)$_{2}$ (2)] were prepared and structurally characterized by X-ray crystallography. These two complexes both displayed 3D structure under the hydrogen bond interaction of N–H···O and C–H···O.
Starting Page	87
Ending Page	92
Page Count	6
File Format	PDF
ISSN	10741542
Journal	Journal of Chemical Crystallography
Volume Number	40
Issue Number	2
e-ISSN	15728854
Language	English
Publisher	Springer US
Publisher Date	2009-09-16
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Crystal structure N,N′-Butylenebis(imidazole) Hydrogen bonds Inorganic Chemistry Physical Chemistry Crystallography Organometallic Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics

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