NDLI: Ortho-metalation and carboxylate coordination in the reaction between the dipotassium salt of phthalic acid and Cp$^{*}$Ir(PMe$_{3}$)Cl$_{2}$: X-ray diffraction structure of Cp*Ir(PMe$_{3}$)[C$_{6}$H$_{3}$(CO$_{2}$)(CO$

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Construction of a hexanuclear cluster composed of spatially separated Co$_{3}$ and Ru$_{3}$ units: X-ray diffraction structure of Co$_{3}$(CO)$_{9}$[μ$_{3}$-CCO$_{2}$CH$_{2}$CC{HRu$_{3}$(CO)$_{9}$}]

Ortho-metalation and carboxylate coordination in the reaction between the dipotassium salt of phthalic acid and Cp$^{*}$Ir(PMe$_{3}$)Cl$_{2}$: X-ray diffraction structure of Cp*Ir(PMe$_{3}$)[C$_{6}$H$_{3}$(CO$_{2}$)(CO$_{2}$H)]

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Ortho-metalation and carboxylate coordination in the reaction between the dipotassium salt of phthalic acid and Cp$^{}$Ir(PMe$_{3}$)Cl$_{2}$: X-ray diffraction structure of CpIr(PMe$_{3}$)[C$_{6}$H$_{3}$(CO$_{2}$)(CO$_{2}$H)]

Content Provider	Springer Nature Link
Author	Watson, William H. Don, Ming Jaw Richmond, Michael G.
Copyright Year	2003
Abstract	The cyclopentadienyl complex CpIr(PMe$_{3}$)Cl$_{2}$ reacts with the dipotassium salt of phthalic acid in the presence of AgPF$_{6}$ via chloride substitution to give the ortho-metalated compound CpIr(PMe$_{3}$)[C$_{6}$H$_{3}$(CO$_{2}$)(CO$_{2}$H)]. This new compound has been isolated by recrystallization and has been characterized in solution by $^{1}$H and $^{13}$C NMR spectroscopies, and the solid-state structure has been verified by X-ray crystallography. Cp*Ir(PMe$_{3}$)[C$_{6}$H$_{3}$(CO$_{2}$)(CO$_{2}$H)] crystallizes in the monoclinic space group P2$_{1}$/c, a = 9.1010(6) Å, b = 16.715(1) Å, c = 14.3965(9) Å, β = 108.24(1)°, V = 2080.0(2) Å$^{3}$, Z = 4, and d $_{calc}$ = 1.813 mg/m$^{3}$; R = 0.0276, R $_{w}$ = 0.0810 for 2730 reflections with I > 2σ(I). Coordination of the benzene ring to the iridium center via one of the carboxylate groups and ortho-metalation of the C–H moiety that was α to the iridium-bound carboxylate group is confirmed.
Starting Page	963
Ending Page	968
Page Count	6
File Format	PDF
ISSN	10741542
Journal	Journal of Chemical Crystallography
Volume Number	33
Issue Number	12
e-ISSN	15728854
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2003-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Inorganic Chemistry Organometallic Chemistry Physical Chemistry Crystallography
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics

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Ortho-metalation and carboxylate coordination in the reaction between the dipotassium salt of phthalic acid and Cp$^{}$Ir(PMe$_{3}$)Cl$_{2}$: X-ray diffraction structure of CpIr(PMe$_{3}$)[C$_{6}$H$_{3}$(CO$_{2}$)(CO$_{2}$H)]

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Ortho-metalation and carboxylate coordination in the reaction between the dipotassium salt of phthalic acid and Cp$^{*}$Ir(PMe$_{3}$)Cl$_{2}$: X-ray diffraction structure of Cp*Ir(PMe$_{3}$)[C$_{6}$H$_{3}$(CO$_{2}$)(CO$_{2}$H)]

Ortho-metalation and carboxylate coordination in the reaction between the dipotassium salt of phthalic acid and Cp$^{}$Ir(PMe$_{3}$)Cl$_{2}$: X-ray diffraction structure of CpIr(PMe$_{3}$)[C$_{6}$H$_{3}$(CO$_{2}$)(CO$_{2}$H)]