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| Content Provider | Springer Nature Link |
|---|---|
| Author | Han, Jing Zeng, Hong Yan Cao, Xi Chen, Chao Rong |
| Copyright Year | 2016 |
| Abstract | The [Fe(CN)$_{6}$]$^{3−}$ intercalated Mg/Fe-LDH (LDH-CN) thin film was prepared by the intercalation-reconstruction method. By using a three-electrode system, the electrochemical performance of the film was also investigated to evaluate the cycling stability for its potential as electrode materials. The LDH-CN thin film was characterized by XRD, FT-IR, SEM and TG-DSC, indicating that the microstructure and surface morphology of the films remained basically unchanged before and after CV scanning for 50 cycles. Redox cycling of the LDH-CN/GCE kept a strong stability at 100 mV s$^{−1}$ for 50 cycles by virtue of the stability of the microstructure of the LDH-CN thin film. Such stability was likely imparted by the formation of a network of mixed-valent Fe$^{2+/3+}$ oxo-bridges that underwent chemical reactions and electrochemical reactions as main capacitive charge storage ions. The LDH-CN electrode presented a maximum specific capacity of 147.2 mAh g$^{−1}$ and excellent cycle life, while it still exhibited 133.9 mAh g$^{−1}$ at the 1000th cycle at a current density of 3 A g$^{−1}$. Such a thin-film electrode made up of the LDH-CN material may be a potential economical alternative battery-type electrode material and possess electrochemical capacitors possibilities. |
| Starting Page | 2754 |
| Ending Page | 2762 |
| Page Count | 9 |
| File Format | |
| ISSN | 09574522 |
| Journal | Journal of Materials Science: Materials in Electronics |
| Volume Number | 28 |
| Issue Number | 3 |
| e-ISSN | 1573482X |
| Language | English |
| Publisher | Springer US |
| Publisher Date | 2016-10-14 |
| Publisher Place | New York |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Optical and Electronic Materials Characterization and Evaluation of Materials |
| Content Type | Text |
| Resource Type | Article |
| Subject | Atomic and Molecular Physics, and Optics Biomaterials Biophysics Condensed Matter Physics Electronic, Optical and Magnetic Materials Bioengineering Electrical and Electronic Engineering Biomedical Engineering |
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