NDLI: Effect of the level of addition of Nb$_{2}$O$_{5}$/Co$_{2}$O$_{3}$ and Ba(Nb$_{2/3}$Co$_{1/3}$)O$_{3}$ on the structure, microstructure, and dielectric properties of BaTiO$

Content Provider	Springer Nature Link
Author	Beitollahi, A. Mortazavi, S. A.
Copyright Year	2003
Abstract	In this work attempt is made to study the effects of the level of the addition of two dopant systems, that is, Nb$_{2}$O$_{5}$/Co$_{2}$O$_{3}$ and Ba(Nb$_{2/3}$Co$_{1/3}$)O$_{3}$ on the structure, microstructure, and dielectric properties of BaTiO$_{3}$(BT) prepared by ceramic route. For the BT samples doped with 2 and 3 at % Nb$_{2}$O$_{5}$/Co$_{2}$O$_{3}$ a broad maxima for ε$_{r}$–T variations was observed. Higher levels of addition, that is, 6, 8, and 10 at % Nb$_{2}$O$_{5}$/Co$_{2}$O$_{3}$, however, caused a drastic reduction in the magnitude of ε$_{r}$ and vanishing of maxima peaks observed. The reduction in the magnitudes of the ε$_{r}$ for these samples is related to the observed reduction of the tetragonality of doped BT samples as well as the existence of some non-ferroelectric extra phase, evidenced by our XRD analysis. The existence of this extra phase is also believed to be mainly responsible for the observed increase of the dielectric loss. For the BT samples doped with Ba(Nb$_{2/3}$Co$_{1/3}$)O$_{3}$ perovskite solid solution, the ε$_{r}$ maxima peak could only be detected for the samples doped with 2 at %. In the case of the samples doped with 4, 6, 8, and 10 at % perovskite solid solution, however, a very uniform distribution of ε$_{r}$–T was observed. The increase of the level of dopant for these series of samples was also seen to give rise in the reduction of the magnitude of ε$_{r}$. However, this reduction was not as strong as the cases observed for the samples doped with 8 and 10 at % Nb$_{2}$O$_{5}$/Co$_{2}$O$_{3}$. XRD patterns obtained for these series of samples also revealed the reduction of tetragonality of the BT samples when doped with Ba(Nb$_{2/3}$Co$_{1/3}$)O$_{3}$. Further, microstructural studies carried out by scanning electron microscopy (SEM) on both series of samples revealed a contrasting picture. While a uniform grain size distribution was observed for the whole series of the samples doped with Ba(Nb$_{2/3}$Co$_{1/3}$)O$_{3}$, a non-uniform size distribution of grain sizes was observed in the case of samples doped with Nb$_{2}$O$_{5}$/Co$_{2}$O$_{3}$. This is thought to be due to the possible formation and non-uniform distribution of a liquid phase due to the formation of Ti-rich region in the shell region of Nb$_{2}$O$_{5}$/Co$_{2}$O$_{3}$-doped samples. The existence of such liquid phase, in case of Nb$_{2}$O$_{5}$/Co$_{2}$O$_{3}$-doped samples, would have the consequence of an increased rate of diffusion of Nb/Co into the BT cores leaving narrow compositional fluctuations for the shell regions.
Starting Page	129
Ending Page	134
Page Count	6
File Format	PDF
ISSN	09574522
Journal	Journal of Materials Science: Materials in Electronics
Volume Number	14
Issue Number	3
e-ISSN	1573482X
Language	English
Publisher	Kluwer Academic Publishers
Publisher Date	2003-01-01
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Optical and Electronic Materials Characterization and Evaluation Materials
Content Type	Text
Resource Type	Article
Subject	Atomic and Molecular Physics, and Optics Biomaterials Biophysics Condensed Matter Physics Electronic, Optical and Magnetic Materials Bioengineering Electrical and Electronic Engineering Biomedical Engineering

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