NDLI: Large-scale synthesis of silver nanowires via a solvothermal method

Content Provider	Springer Nature Link
Author	Chen, Dapeng Qiao, Xueliang Qiu, Xiaolin Chen, Jianguo Jiang, Renzhi
Copyright Year	2010
Abstract	Silver nanostructures have been synthesized through a simple solvothermal method by reducing silver nitrate (AgNO$_{3}$) with ethylene glycol (EG) and using poly(vinylpyrrolidone) (PVP) as an adsorption agent. Different concentrations of ferric chloride (FeCl$_{3}$) are added into the solution. It is found that AgCl colloids formed in the initial stage greatly influence the final morphologies of the products. When a low-concentration FeCl$_{3}$ solution is used, there is a mixture of silver nanoparticles and nanowires. However, when a high-concentration FeCl$_{3}$ solution (100 μM) is used, large amounts of AgCl colloids appear, resulting in decreasing free Ag$^{+}$ during initial formation of silver seeds and slowly releasing of Ag$^{+}$ to the solution in the subsequent reaction. This leads to the formation of silver nanowires. Furthermore, an increase in the concentration of FeCl$_{3}$ from 100 to 300 μM results in the synthesis of silver nanowires with larger sizes. In addition, Fe(III) is reduced to Fe(II) form which in turn reacts with and removes adsorbed atomic oxygen from the surface of silver seeds. In this case, uniform silver nanowires can be obtained.
Starting Page	6
Ending Page	13
Page Count	8
File Format	PDF
ISSN	09574522
Journal	Journal of Materials Science: Materials in Electronics
Volume Number	22
Issue Number	1
e-ISSN	1573482X
Language	English
Publisher	Springer US
Publisher Date	2010-02-09
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Characterization and Evaluation of Materials Optical and Electronic Materials
Content Type	Text
Resource Type	Article
Subject	Atomic and Molecular Physics, and Optics Biomaterials Biophysics Condensed Matter Physics Electronic, Optical and Magnetic Materials Bioengineering Electrical and Electronic Engineering Biomedical Engineering

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