NDLI: Enhancement of poly(3,4-ethylenedioxy thiophene)/poly(styrene sulfonate) properties by poly(vinyl alcohol) and doping agent as conductive nano-thin film for electronic application

Content Provider	Springer Nature Link
Author	Romyen, Nathavat Thongyai, Supakak Praserthdam, Piyasan Sotzing, Gregory A.
Copyright Year	2013
Abstract	In this work, the integration of the useful concepts of polymer blending and doping agent to simultaneously improve various properties of poly(3,4-ethylene dioxy thiophene) poly(styrene sulfonate) (PEDOT:PSS) nano-thin films was shown. According to the polymer-blending concept, insulating poly(vinyl alcohol) (PVA) has a good deal of potential to be utilized as a filler to improve the critical properties of the PEDOT:PSS matrix, especially conductivity, wettability, and thermal and mechanical properties. At the appropriate amount of PVA, 0.08 wt%, it acts as a binder to improve the connection network between PEDOT:PSS chains, leading to a maximum conductivity of 1.18 S/cm, and also providing a good contact angle of 8.8°. The transmission of the films decreased with increasing PVA content; however, all specimens still showed excellent transmittance values of more than 80 %. The thermal stability and the resistance to abrasion of the nano-thin conductive films were improved by strong covalent bonds between PVA and PSS, which were verified by TGA and a scratching test, respectively. In addition, the relationship of PEDOT:PSS properties versus various amounts of insulating PVA for practical usage for specific electronic fields were shown. Use of the doping agent quinoxaline was aimed to particularly enhance the conductivity of PEDOT:PSS. The highest conductivity (2.75 S/cm) was achieved when 0.5 wt% quinoxaline was added into 0.08 wt% PVA/PEDOT:PSS while the other properties were not significantly altered.
Starting Page	2897
Ending Page	2905
Page Count	9
File Format	PDF
ISSN	09574522
Journal	Journal of Materials Science: Materials in Electronics
Volume Number	24
Issue Number	8
e-ISSN	1573482X
Language	English
Publisher	Springer US
Publisher Date	2013-03-23
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Optical and Electronic Materials Characterization and Evaluation of Materials
Content Type	Text
Resource Type	Article
Subject	Atomic and Molecular Physics, and Optics Biomaterials Biophysics Condensed Matter Physics Electronic, Optical and Magnetic Materials Bioengineering Electrical and Electronic Engineering Biomedical Engineering

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