NDLI: Effects of solvent system on tape casting of the BaSrTiO$_{3}$-MgO-based dielectric ceramics containing B$_{2}$O$

Content Provider	Springer Nature Link
Author	Wang, Can Ji, Huiming Wang, Jian
Copyright Year	2011
Abstract	Ba$_{0.6}$Sr$_{0.4}$TiO$_{3}$-MgO-based ceramic slurries with B$_{2}$O$_{3}$ and Li$_{2}$CO$_{3}$ as sintering aid were prepared with different solvent systems for tape casting application. The effects of azeotropic mixtures of toluene–ethanol, methyl ethyl ketone (MEK)–ethanol and zeotrpic mixture of xylene–ethanol with a mass ratio of 50:50 on Ba$_{0.6}$Sr$_{0.4}$TiO$_{3}$-MgO-based nonaqueous suspensions with B$_{2}$O$_{3}$ and Li$_{2}$CO$_{3}$ as sintering aid were investigated by sedimentation test, rheological measurement, density measurement, and SEM analysis. Without organic additives added, suspensions prepared with the MEK–ethanol mixture present higher flowability with lower viscosity, but less stability because of the smaller viscosity and density of MEK. On the other hand, with organic additives added, the gel structure is formed in slurries prepared with the toluene–ethanol mixture and xylene–ethanol mixture, caused by the reaction of the functional hydroxyl group of PVB and dissociated borate in the slurries. While slurries prepared with the MEK–ethanol mixture were more stable, exhibiting nearly Newtonian flow behavior and significantly lower viscosity.
Starting Page	2486
Ending Page	2491
Page Count	6
File Format	PDF
ISSN	00222461
Journal	Journal of Materials Science
Volume Number	47
Issue Number	5
e-ISSN	15734803
Language	English
Publisher	Springer US
Publisher Date	2011-11-03
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Materials Science Mechanics Polymer Sciences Characterization and Evaluation of Materials Crystallography Continuum Mechanics and Mechanics of Materials
Content Type	Text
Resource Type	Article
Subject	Ceramics and Composites Mechanics of Materials Mechanical Engineering Polymers and Plastics

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