NDLI: Piezoelectric properties and conductivity of Pb(Zr,Ti)O$_{3}$ with SrO–WO$

Content Provider	Springer Nature Link
Author	Reichmann, Klaus Völkl, Elmar Ahrens, Martin Fleig, Jürgen Vötsch, Jürgen
Copyright Year	2009
Abstract	The influence of SrO–WO$_{3}$ additive on the piezoelectric properties and electric conductivity of lead zirconate–titanate (PZT) near the morphotropic phase boundary was investigated. Starting from the composition 0.995 Pb(Zr$_{0.525}$Ti$_{0.475}$)O$_{3}$ + 0.015 SrO + 0.005 WO$_{3}$ (corresponding to 0.5 mol% of Sr$_{3}$WO$_{6}$) the fraction of WO$_{3}$ was increased until Sr:W = 1:1. These samples were compared to a set of samples of PZT with WO$_{3}$ addition but without SrO. Sr$_{3}$WO$_{6}$ has pseudocubic K$_{2}$NaAlF$_{6}$ structure with part of the strontium being octahedrally coordinated. In a solid solution with PZT this opens the possibility of realizing Sr on a B-site adjacent to a B-site occupied by W. Piezoelectric properties were measured on sintered disc samples under high field conditions. Impedance spectroscopy was used to investigate the conductivity and dielectric properties of the ceramics at various temperatures. The combined addition of SrO and WO$_{3}$ increases the piezoelectric strain compared to samples of PZT with WO$_{3}$ addition only. The results in polarization and conductivity indicate that the donor effect of WO$_{3}$ is counteracted by the addition of SrO.
Starting Page	1473
Ending Page	1477
Page Count	5
File Format	PDF
ISSN	00222461
Journal	Journal of Materials Science
Volume Number	45
Issue Number	6
e-ISSN	15734803
Language	English
Publisher	Springer US
Publisher Date	2009-12-11
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Mechanics Crystallography Continuum Mechanics and Mechanics of Materials Polymer Sciences Characterization and Evaluation of Materials Materials Science
Content Type	Text
Resource Type	Article
Subject	Ceramics and Composites Mechanics of Materials Mechanical Engineering Polymers and Plastics

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