NDLI: Effect of Co and Ce on silica supported manganese catalysts in the reactions of complete oxidation of n-hexane and ethyl acetate

Content Provider	Springer Nature Link
Author	Todorova, S. Naydev, A. Kolev, H. Tenchev, K. Ivav, G. Kadiv, G.
Copyright Year	2011
Abstract	Mono-component and bi-component catalysts, prepared by impregnation of silica with aqueous solution of Mn, Co, and Ce nitrates, were tested in the reactions of complete oxidation of n-hexane and ethyl acetate. The catalysts were characterized by powder X-ray diffraction, temperature-programmed reduction, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy (FTIR). The catalytic activity is significantly increased by the combination between manganese and cobalt, which is explained as a result of the high mobility of lattice oxygen, the simultaneous presence of Mn$^{4+}$–Mn$^{3+}$ couple, decrease in the strength of the Co–O bond, and the predominance of Co in the second oxidation state on the catalyst surface. The decrease in catalytic activity of Mn–Ce sample is attributed to the predominance of Ce on the surface and lower mobility of the lattice oxygen.
Starting Page	7152
Ending Page	7159
Page Count	8
File Format	PDF
ISSN	00222461
Journal	Journal of Materials Science
Volume Number	46
Issue Number	22
e-ISSN	15734803
Language	English
Publisher	Springer US
Publisher Date	2011-06-01
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Materials Science Polymer Sciences Characterization and Evaluation of Materials Continuum Mechanics and Mechanics of Materials Mechanics Crystallography
Content Type	Text
Resource Type	Article
Subject	Ceramics and Composites Mechanics of Materials Mechanical Engineering Polymers and Plastics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Particle size and support effects on the complete benzene oxidation by Co and Co–Pt catalysts

Iron supported clay as catalysts for oxidation of cyclooctane

Mesocarbon microbeads supported PtSn catalysts for electrochemical oxidation of ethanol

Total oxidation of volatile organic compounds on Au/Ce–Ti–O and Au/Ce–Ti–Zr–O mesoporous catalysts

Mesoporous Ce$_{0.8}$Zr$_{0.2}$O$_{2}$ solid solutions-supported CuO nanocatalysts for CO oxidation: a comparative study of preparation methods

Hierarchical meso–macroporous titania-supported CuO nanocatalysts: preparation, characterization and catalytic CO oxidation

Porous silica as host for PEG-supported coumarin molecules

Dual templates assisted preparation and characterization of highly thermostable multicomponent mesoporous material La–Ce–Co–Zr–O used for low-temperature CO oxidation

Solvothermal synthesis in ethylene glycol and catalytic activity for CO oxidation of CuO/CeO$_{2}$ catalysts

Effect of Co and Ce on silica supported manganese catalysts in the reactions of complete oxidation of n-hexane and ethyl acetate

Similar Documents

Particle size and support effects on the complete benzene oxidation by Co and Co–Pt catalysts

Iron supported clay as catalysts for oxidation of cyclooctane

Mesocarbon microbeads supported PtSn catalysts for electrochemical oxidation of ethanol

Total oxidation of volatile organic compounds on Au/Ce–Ti–O and Au/Ce–Ti–Zr–O mesoporous catalysts

Mesoporous Ce$_{0.8}$Zr$_{0.2}$O$_{2}$ solid solutions-supported CuO nanocatalysts for CO oxidation: a comparative study of preparation methods

Hierarchical meso–macroporous titania-supported CuO nanocatalysts: preparation, characterization and catalytic CO oxidation

Porous silica as host for PEG-supported coumarin molecules

Dual templates assisted preparation and characterization of highly thermostable multicomponent mesoporous material La–Ce–Co–Zr–O used for low-temperature CO oxidation

Solvothermal synthesis in ethylene glycol and catalytic activity for CO oxidation of CuO/CeO$_{2}$ catalysts

Effect of Co and Ce on silica supported manganese catalysts in the reactions of complete oxidation of n-hexane and ethyl acetate