NDLI: Morphology, mechanical and thermal behavior of acrylate rubber/fluorocarbon elastomer/polyacrylate blends

Content Provider	Springer Nature Link
Author	Kader, M. Abdul Bhowmick, A. K. Iue, T. Chiba, T.
Copyright Year	2002
Abstract	Novel thermoplastic elastomers derived from binary and ternary blends of polyfunctional acrylates, acrylic rubber (ACM) and fluorocarbon rubber (FKM) were analyzed by using Transmission Electron Microscopy (TEM), Differential Scanning Calorimetry (DSC), Dynamic Mechanical Thermal Analysis (DMTA) and mechanical tests. TEM revealed the presence of a single-phase structure for both acrylate rubber/fluorocarbon elastomer (ACM/FKM) and ACM/polyacrylate binary blends. Increase of FKM concentration in the ACM/FKM/polyacrylate ternary blend resulted in phase separation of FKM from the ternary blend. The FKM formed a dispersed phase with polynodal particle distribution and irregular shape ranging from ellipsoidal to highly elongated form with inclusion of ACM. The FKM/polyacrylate binary blend showed complete phase separation. Ageing of the blend increased the domain size of the dispersed phase. Differential scanning calorimetric (DSC) and DMTA studies showed no major changes in the T $_{g}$s of individual polymers in the blend, although the peak tan δ values were affected on changing the composition of the blends. Vulcanization of the thermoplastic elastomer (TPE) changed the phase morphology with increase in particle size. There is a distinct difference in morphology of statically and dynamically vulcanized blends.
Starting Page	1503
Ending Page	1513
Page Count	11
File Format	PDF
ISSN	00222461
Journal	Journal of Materials Science
Volume Number	37
Issue Number	8
e-ISSN	15734803
Language	English
Publisher	Kluwer Academic Publishers
Publisher Date	2002-01-01
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Polymer Sciences Materials Science Characterization and Evaluation Materials Mechanics Crystallography Continuum Mechanics and Mechanics of Materials
Content Type	Text
Resource Type	Article
Subject	Ceramics and Composites Mechanics of Materials Mechanical Engineering Polymers and Plastics

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