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| Content Provider | Springer Nature Link |
|---|---|
| Author | Zhevnenko, S. N. Vagav, D. V. Gershman, E. I. |
| Copyright Year | 2011 |
| Abstract | As well known, bismuth rapidly penetrates into copper grain boundaries at about 550 °C and embrittles copper. In the experiments, the authors have used solid Bi$_{2}$Te$_{3}$ for the embrittlement of pure copper and copper-based solid solutions containing iron and silver. The investigated alloys were heated in the closed volume together with Bi$_{2}$Te$_{3}$ for a short time (5–90 min) at 570 °C in the hydrogen atmosphere. Bi$_{2}$Te$_{3}$ did not contact with copper samples during annealing. After that, the samples were bent and grain boundary cracks were formed (with the depth about 10–500 μm). Experiment showed that silver accelerates the embrittlement in the contrast to iron. The cracks in the silver–copper alloys were deeper than in the iron–copper ones. It was assumed that the depth of cracks is equal to the penetration depth. The reasons for this phenomenon were discussed in terms of the impurities effect on the grain boundary segregation. |
| Starting Page | 4248 |
| Ending Page | 4253 |
| Page Count | 6 |
| File Format | |
| ISSN | 00222461 |
| Journal | Journal of Materials Science |
| Volume Number | 46 |
| Issue Number | 12 |
| e-ISSN | 15734803 |
| Language | English |
| Publisher | Springer US |
| Publisher Date | 2011-01-21 |
| Publisher Place | Boston |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Materials Science Mechanics Characterization and Evaluation of Materials Crystallography Continuum Mechanics and Mechanics of Materials Polymer Sciences |
| Content Type | Text |
| Resource Type | Article |
| Subject | Ceramics and Composites Mechanics of Materials Mechanical Engineering Polymers and Plastics |
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