NDLI: Structure and morphology of phenylsilanes polymer films synthesized by the plasma polymerization method

Content Provider	Springer Nature Link
Copyright Year	1998
Abstract	Phenylsilanes were deposited by r.f. glow discharge to investigate the relationship between the synthesis conditions (r.f. power, synthesis time and monomer) and the structure and morphology of plasma-polymerized films. The film deposited at 2.0 W consisted of polycarbosilane-like main chains and side chains corresponding to the monomer structure. The film deposited at higher r.f. power consisted of a polycarbosilane-like main chain with more cross-links and less aromatic groups. The films synthesized at 2.0 W from phenylsilane had many submicrometre sized particles on the surface, but the films synthesized from phenylsilanes with methyl groups had few particles and smooth surfaces. The films deposited at higher r.f. power had many particles on their surfaces. The infrared spectra of methylphenylsilane polymer films were independent of the synthesis time, but film surface morphology changed from a smooth surface into a granular surface with an increase in the synthesis time. © 1998 Chapman & Hall
Starting Page	1897
Ending Page	1905
Page Count	9
File Format	PDF
ISSN	00222461
Journal	Journal of Materials Science
Volume Number	33
Issue Number	7
e-ISSN	15734803
Language	English
Publisher	Kluwer Academic Publishers
Publisher Date	1998-01-01
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Polymer Sciences Industrial Chemistry/Chemical Engineering Characterization and Evaluation Materials Mechanics
Content Type	Text
Resource Type	Article
Subject	Ceramics and Composites Mechanics of Materials Mechanical Engineering Polymers and Plastics

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