NDLI: Preparation and characterization of poly (styrene-acrylonitrile) (SAN)/clay nanocomposites by melt intercalation

Content Provider	Springer Nature Link
Author	Cai, Yibing Hu, Yuan Xuan, Shanyong Zhang, Yi Deng, Huaxia Gong, Xinglong Chen, Zuyao Fan, Weicheng
Copyright Year	2007
Abstract	Poly (styrene-acrylonitrile) (SAN)/clay nanocomposites have been prepared by melt intercalation method from pristine montmorillonite (MMT), using hexadecyl trimethyl ammonium bromide (C16) and hexadecyl triphenyl phosphonium bromide (P16) as the reactive compatibilizers between polymer and clay. The influence of the reactive compatibilizers proportion relative to the clay on the structure and properties of the SAN/clay nanocomposites is investigated by X-ray diffraction (XRD) and transmission electron microscopy (TEM), high-resolution electron microscopy (HREM), thermogravimetric analysis (TGA) and dynamic mechanical analysis (DMA). The effects of the two different clays (MMT and organic modified MMT) on the nanocomposites formation, morphology and property are also studied. The results indicate that the SAN cannot intercalate into the interlayers of the MMT and results in microcomposites. In the presence of the reactive compatibilizers, the dispersion of clay in SAN is rather facile and the SAN/clay nanocomposites reveal an intermediate morphology, an intercalated structure with some exfoliation and the presence of small tactoids. The appropriate proportion with 3 wt% reactive compatibilizers to 5 wt% MMT induces well-dispersed morphology and properties in the SAN matrix. The TGA analyses show that the thermal stability properties of the SAN/clay nanocomposites have been improved compared with those of the pristine SAN. The DMA results show that the storage modulus and glass transition temperature (Tg) of the SAN/clay nanocomposites have remarkably enhancements compared with the pristine SAN. At last the intercalation mechanism of the technology is discussed.
Starting Page	5524
Ending Page	5533
Page Count	10
File Format	PDF
ISSN	00222461
Journal	Journal of Materials Science
Volume Number	42
Issue Number	14
e-ISSN	15734803
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2007-04-03
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Mechanics Crystallography Continuum Mechanics and Mechanics of Materials Polymer Sciences Characterization and Evaluation of Materials Materials Science
Content Type	Text
Resource Type	Article
Subject	Ceramics and Composites Mechanics of Materials Mechanical Engineering Polymers and Plastics

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Preparation and characterization of poly(vinyl chloride) calcium carbonate nanocomposites via melt intercalation

Preparation and characterization of poly (styrene-acrylonitrile) (SAN)/clay nanocomposites by melt intercalation

Ethylene vinyl acetate/expanded graphite nanocomposites by solution intercalation: preparation, characterization and properties

Development of acrylonitrile–butadiene–styrene composites with enhanced UV stability

Plating on acrylonitrile–butadiene–styrene (ABS) plastic: a review

Melt-spun poly(tetrafluoroethylene) fibers

Preparation and tribological properties of graphene/poly(ether ether ketone) nanocomposites

Preparation and physical characteristics of solvent intercalated poly(o-ethoxyaniline)/organoclay nanocomposites

Melt-processable acrylonitrile–methyl acrylate copolymers and melt-spun fibers containing MicroPCMs

Preparation and characterization of poly (styrene-acrylonitrile) (SAN)/clay nanocomposites by melt intercalation

Similar Documents

Preparation and characterization of poly(vinyl chloride) calcium carbonate nanocomposites via melt intercalation

Preparation and characterization of poly (styrene-acrylonitrile) (SAN)/clay nanocomposites by melt intercalation

Ethylene vinyl acetate/expanded graphite nanocomposites by solution intercalation: preparation, characterization and properties

Development of acrylonitrile–butadiene–styrene composites with enhanced UV stability

Plating on acrylonitrile–butadiene–styrene (ABS) plastic: a review

Melt-spun poly(tetrafluoroethylene) fibers

Preparation and tribological properties of graphene/poly(ether ether ketone) nanocomposites

Preparation and physical characteristics of solvent intercalated poly(o-ethoxyaniline)/organoclay nanocomposites

Melt-processable acrylonitrile–methyl acrylate copolymers and melt-spun fibers containing MicroPCMs

Preparation and characterization of poly (styrene-acrylonitrile) (SAN)/clay nanocomposites by melt intercalation