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| Content Provider | Springer Nature Link |
|---|---|
| Author | Saida, J. Matsushita, M. Li, C. Iue, A. |
| Copyright Year | 2000 |
| Abstract | The grain growth behavior of a Zr$_{2}$Cu crystallinephase from a supercooled liquid region of Zr$_{65}$Cu$_{27.5}$Al$_{7.5}$ and Zr$_{65}$Cu$_{35}$ metallic glasses was examined as a function of annealingtime, t $_{a}$ at various temperatures. Since no distinct change ofconstitution and strain in Zr$_{2}$Cu phase is seen, the grain sizecalculated from a line-broadening of X-ray diffraction peak byScherrer's formula can be used. The calculated grain size is inagreement with that obtained by transmission electron microscopyobservation. The curve of grain size with t $_{a}$ is parabolic. The graingrowth in Zr$_{65}$Cu$_{35}$ takes place at lower temperature and its rate isextremely larger as compared with those of Zr$_{65}$Cu$_{27.5}$Al$_{7.5}$. Thesedifferences are originated from the suppression of growth of Zr$_{2}$Cu byAl atom, which retards the diffusion of Cu owing to the primaryprecipitation of ZrAl in Zr$_{65}$Cu$_{27.5}$Al$_{7.5}$. The formation of ZrAl maybe attributed to the strong chemical affinity between Al and Zr. Theactivation energies for grain growth of 115 kJ mol$^{−1}$ forZr$_{65}$Cu$_{27.5}$Al$_{7.5}$ and 363 kJ mol$^{−1}$ for Zr$_{65}$Cu$_{35}$ are obtained by theArrhenius plot of grain growth rate against a reciprocal oftemperature. These activation energies reflect the kind and/ormagnitude of diffusion atoms during the grain growth. |
| Starting Page | 3539 |
| Ending Page | 3546 |
| Page Count | 8 |
| File Format | |
| ISSN | 00222461 |
| Journal | Journal of Materials Science |
| Volume Number | 35 |
| Issue Number | 14 |
| e-ISSN | 15734803 |
| Language | English |
| Publisher | Kluwer Academic Publishers |
| Publisher Date | 2000-01-01 |
| Publisher Place | Boston |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Polymer Sciences Industrial Chemistry/Chemical Engineering Characterization and Evaluation Materials Mechanics |
| Content Type | Text |
| Resource Type | Article |
| Subject | Ceramics and Composites Mechanics of Materials Mechanical Engineering Polymers and Plastics |
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