NDLI: Soluble axially substituted phthalocyanines: Synthesis and nonlinear optical response

Content Provider	Springer Nature Link
Author	Chen, Yu Hanack, Michael Blau, Werner J. Dini, Danilo Liu, Ying Lin, Ying Bai, Jinrui
Copyright Year	2006
Abstract	This review lays special stress on describing the synthesis of soluble axially substituted or bridged indium, gallium and titanium phthalocyanine complexes and their electronic absorption characteristics, photophysical and nonlinear optical properties. The enhanced solubility of the axially substituted or bridged phthalocyanine monomers and dimers, compared to the chloro analogues, shows that the usual tendency of phthalocyanines to form aggregates can be effectively suppressed by axial substitution. Axial substitution in phthalocyanine complexes has provoked relevant changes on the electronic structure of the molecule by altering the π-electronic distribution due to the dipole moment of the central metal-axial ligand bond. The nanosecond nonlinear absorption and the optical limiting of indium, gallium and titanium phthalocyanines seem to be dominated by a strong triplet state absorption in the optical region comprised between the Q- and B-bands in their UV/Vis absorption spectra.A series of highly soluble axially substituted and bridged phthalocyanine and naphthalocyanine complexes have been synthesized. Axial substitution in phthalocyanine complexes has provoked relevant changes on the electronic structure of the molecule by altering the π-electronic distribution due to the dipole moment of the central metal-axial ligand bond.
Starting Page	2169
Ending Page	2185
Page Count	17
File Format	PDF
ISSN	00222461
Journal	Journal of Materials Science
Volume Number	41
Issue Number	8
e-ISSN	15734803
Language	English
Publisher	Kluwer Academic Publishers
Publisher Date	2006-04-05
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Polymer Sciences Materials Science Characterization and Evaluation Materials Mechanics Continuum Mechanics and Mechanics of Materials Crystallography
Content Type	Text
Resource Type	Article
Subject	Ceramics and Composites Mechanics of Materials Mechanical Engineering Polymers and Plastics

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