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| Content Provider | Springer Nature Link |
|---|---|
| Author | Yawei, Li Nan, Li Runzhang, Yuan |
| Copyright Year | 1999 |
| Abstract | The effect of starting Al$_{2}$O$_{3}$ materials on synthesis of γ-aluminum oxynitride spinel (γ-AlON) powder by carbothermal reduction has been investigated. Whether using Al(OH)$_{3}$, boehmite, dried gel, or calcined alumina as an alumina source, the reaction rate is faster than that using α-Al$_{2}$O$_{3}$. That is because the oxygen distribution in γ-Al$_{2}$O$_{3}$ is cubic close packed as the non-metal arrangement in AlON spinel is whereas that in α-Al$_{2}$O$_{3}$ is hexagonal close packed. When hydrated aluminas used lose structural water and transform into γ-Al$_{2}$O$_{3}$ in heating cycle, γ-Al$_{2}$O$_{3}$ is easily reduced and nitrided into AlON spinel after a slight adjustment in the cation positions and proportions is made in the reduction process of alumina. The particle morphology of the product after carbothermal reduction was strongly influenced by the type of alumina source employed, which suggests the mechanism of Al$_{2}$O$_{3}$/C powder mixtures in a flowing N$_{2}$ stream is the absorption of aluminum-containing gas, such as Al(g), Al$_{2}$O(g), etc., on the surface of aluminum oxide in the initial stages, followed by reaction with N$_{2}$ gas to form AlON and AlN phases with nucleation, and growth on Al$_{2}$O$_{3}$ particle surfaces. |
| Starting Page | 2547 |
| Ending Page | 2552 |
| Page Count | 6 |
| File Format | |
| ISSN | 00222461 |
| Journal | Journal of Materials Science |
| Volume Number | 34 |
| Issue Number | 11 |
| e-ISSN | 15734803 |
| Language | English |
| Publisher | Kluwer Academic Publishers |
| Publisher Date | 1999-01-01 |
| Publisher Place | Boston |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Polymer Sciences Industrial Chemistry/Chemical Engineering Characterization and Evaluation Materials Mechanics |
| Content Type | Text |
| Resource Type | Article |
| Subject | Ceramics and Composites Mechanics of Materials Mechanical Engineering Polymers and Plastics |
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