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  1. Journal of Inclusion Phenomena and Macrocyclic Chemistry
  2. Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 54
  3. Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 54, Issue 1-2, February 2006
  4. Chemical Oxidative Polymerization of β-Cyclodextrin/Aniline Inclusion Complex
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Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 88
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 87
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 86
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 85
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 84
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 83
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 82
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 81
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 80
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 79
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 78
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 77
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 76
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 75
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 74
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 73
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 72
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 71
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 70
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 69
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 68
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 67
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 66
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 65
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 64
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 63
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 62
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 61
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 60
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 59
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 58
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 57
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 56
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 55
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 54
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 54, Issue 3-4, April 2006
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 54, Issue 1-2, February 2006
Calixarene-Based Dendrimers. A Timely Review
Equimolar Complex Formation of Urea or Thiourea with 2-alkoxy-benzamides: Structural Factors Required for the Equimolar Complex Formation
Inclusion Complexes of Felodipine and Amlodipine with Methyl-β-cyclodextrin
Nickel(macrocycle) Complexes Immobilized within Montmorillonite and MCM-41 as Catalysts for Epoxidation of Olefins
Synthesis of Novel Chiral C$_{2}$-symmetric Diaza-18-crown-6 Ether Derivatives and their Enantioselective Recognition of Amino Acid Derivatives
Competition between the Hydrated Fluoride Anion and Hexanoic Acid for Inclusion in β-Cyclodextrin: An $^{1}$H-NMR Study in Aqueous Solution
Enantioselective Oxidation of Sulfides Catalyzed by Chiral Mo$^{V}$ and Cu$^{II}$ Complexes of Catechol-Appended β-Cyclodextrin Derivatives in Water
Ternary Complexes of Lanthanide–Calix[4]Arene with Sulphophthalein Dyes
Mass Spectrometric Determination of Association Constants of Bovine Serum Albumin (BSA) with para-Sulphonato-Calix[n]arene Derivatives
Biphenyl Macrolactams as Colorimetric Sensors for Anions through Displacement Reactions
Interactions of Tetrakis(4-sulfonatophenyl)porphyrin with γ-Cyclodextrin and Alkyltrimethylammonium Bromides in Aqueous Solutions
Structural Elucidation of {[(CH$_{3}$)$_{2}$SnCl$_{2}$·H$_{2}$O]$_{2}$·18-crown-6}$_{n}$ and its Hydrogen Bonding in Solution by HMBC Spectroscopy
One-step Synthesis of p-tert-Butylcalix[6]-1,4-2,5- biscrown-4 and its Tosyloxyethoxyethylate Derivative
Structure, Electronic Properties and NMR-Shielding of Cucurbit[n]urils
Features of the Interaction between Cyclodextrins and Colloidal Liposomes
A Spectral and Molecular Dynamics Simulation Study of β-Cyclodextrin Inclusion Complexes with Solvatochromic Dyes Derived from Barbituric Acid
Chemical Oxidative Polymerization of β-Cyclodextrin/Aniline Inclusion Complex
Formation of Cyclodextrin Inclusion Complexes with Doxycyclin-Hyclate: NMR Investigation of Their Characterisation and Stability
Synthesis and Characterization of One-dimensional Dicyclohexyl-18-crown-6 Complexes with M$_{2}$[Cd(mnt)$_{2}$] (M = Na, K)
Molecular Mechanics Study of the Inclusion Complexes of Some 1,2,4-Oxadiazole Derivatives of 3,3′-Bis (1,2,4-Oxadiazol-5(4H)-one) with β-Cyclodextrin
Acetate-Selective Anion Receptor with Methylene-Bridged Bis-Imidazolium Rings
An Inclusion Compound of the Anticonvulsant Sodium Valproate into α-Cyclodextrin: Physico-Chemical Characterization
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 53
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 52
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 51
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 50
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 49
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 48
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 47
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 46
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 45
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 44
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 43
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 42
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 41
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 40
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 39
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 38
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 37
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 36
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 35
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 34
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 33
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 32
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 31
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 30
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 29
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 28
Journal of Inclusion Phenomena and Macrocyclic Chemistry : Volume 27

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Chemical Oxidative Polymerization of β-Cyclodextrin/Aniline Inclusion Complex

Content Provider Springer Nature Link
Author Grigoras, Mircea Conduruta, Daniel Gheorghe
Copyright Year 2006
Abstract A β-cyclodextrin (β-CD)/aniline inclusion complex has been synthesized in aqueous solution and characterized by FT-IR and $^{1}$H-NMR spectroscopy, chemical analysis and thermogravimetric method. By elemental analysis and $^{1}$H-NMR spectroscopy a complex with stoichiometry 1:1.95 and 1:1.8 (β-CD/aniline) respectively, is found. The complexed aniline was polymerized by chemical oxidative polymerization using ammonium peroxydisulfate in water (pH = 7) and 1M HCl aqueous solution. In both cases, after an induction period, insoluble polyanilines (PANIs) are obtained, however, in water at pH = 7, a polypseudorotaxane architecture containing a β-CD molecule to ~14 aniline units has resulted. In acidic conditions, anilinium cation is highly hydrophilic and inclusion complex has a strong tendency to dissociate to free molecules and emeraldine salt of PANI, free of host molecules is synthesized.
Starting Page 101
Ending Page 107
Page Count 7
File Format PDF
ISSN 09230750
Journal Journal of Inclusion Phenomena and Macrocyclic Chemistry
Volume Number 54
Issue Number 1-2
e-ISSN 15731111
Language English
Publisher Kluwer Academic Publishers
Publisher Date 2006-01-01
Publisher Place Dordrecht
Access Restriction One Nation One Subscription (ONOS)
Subject Keyword β-cyclodextrin/aniline inclusion complex chemical oxidative polymerization pseudorotaxane architecture Food Science Organic Chemistry Crystallography
Content Type Text
Resource Type Article
Subject Chemistry Condensed Matter Physics Food Science
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