NDLI: O-Ethoxycarbonylmethoxy esters of homocalix[n]naphthalenes: synthesis and recognition behaviour towards alkali cations

Content Provider	Springer Nature Link
Author	Tran, Huu Anh Ashram, Muhammad Mizyed, Shehadeh Thompson, David W. Georghiou, Paris E.
Copyright Year	2007
Abstract	The condensation of 1,2-bis(3-hydroxy-2-naphthyl)ethane and formaldehyde under basic conditions was successfully employed for the synthesis of two new large-ring n-homocalixnaphthalenes 5 and 6. The synthetic yields using a relatively larger reaction scale were higher than those obtained by the sulphur extrusion approach. O-Alkylation of these homocalixnaphthalenes afforded the corresponding hexa- and octa-O-ester derivatives 5a and 6a respectively. The new naphthalene-ring based macrocycle 5a demonstrated high extraction capability for K$^{+}$ under the conditions studied. O -Ethoxycarbonylmethoxy esters of homocalix[ n ]naphthalenes: synthesis and recognition behaviour towards alkali cations Huu-Anh Tran, Muhammad Ashram, Shehadeh Mizyed, David W. Thompson and Paris E. Georghiou* The condensation of 1,2-bis(3-hydroxy-2-naphthyl)ethane and formaldehyde under basic conditions was successfully employed for the synthesis of two new large-ring n-homocalixnaphthalenes 5 and 6.
Starting Page	43
Ending Page	49
Page Count	7
File Format	PDF
ISSN	09230750
Journal	Journal of Inclusion Phenomena and Macrocyclic Chemistry
Volume Number	60
Issue Number	1-2
e-ISSN	15731111
Language	English
Publisher	Springer Netherlands
Publisher Date	2007-09-06
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Calixarenes Homocalixarenes Calixnaphthalenes Homocalixnaphthalenes Alkali metal complexation Crystallography Food Science Organic Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Food Science

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