NDLI: Hydrogen production by aqueous phase reforming of sorbitol using bimetallic Ni

Content Provider	Springer Nature Link
Author	Tanksale, A. Zhou, C. H. Beltramini, J. N. Lu, G. Q.
Copyright Year	2009
Abstract	Hydrogen was produced by Aqueous Phase Reforming (APR) of 10% (w/w) sorbitol using mono- and bi-metallic catalysts of Ni and Pt supported on alumina nano-fibre (Alnf), mesoporous ZrO$_{2}$ and mixed oxides of ceria–zirconia–silica (CZxS) with varying concentration of silica (where x is silica concentration). X-ray diffraction, TEM/EDS and temperature programmed reduction were also carried on these catalysts to study the surface properties. It was observed that co-impregnation of Pt and Ni in atomic ratio 1:12 increased the reducibility of Ni by forming an alloy. However, sequential impregnation of Ni followed by Pt does not form the bi-metallic particles to increase the Ni reducibility. Reduction peak of co-impregnated Ni–Pt/Alnf was found to be 270 °C lower than the sequentially impregnated Pt/Ni/Alnf. The presence of silica at high concentration in CZxS support decreased the reducibility of ceria by forming an amorphous layer on Ce$_{x}$Zr$_{1−x}$O$_{2}$ crystals, which also decreased Ni reducibility. The rate of H$_{2}$ formation from aqueous phase sorbitol reforming was found to be highest for co-impregnated Ni–Pt catalysts followed by sequentially impregnated Pt/Ni and monometallic Ni catalyst. The H$_{2}$ activity decreased in the following order of the supports: Alnf > ZrO$_{2}$ > CZ3S > CZ7S.
Starting Page	83
Ending Page	88
Page Count	6
File Format	PDF
ISSN	09230750
Journal	Journal of Inclusion Phenomena and Macrocyclic Chemistry
Volume Number	65
Issue Number	1-2
e-ISSN	15731111
Language	English
Publisher	Springer Netherlands
Publisher Date	2009-07-10
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Bimetallic Ni–Pt catalyst Aqueous phase sorbitol reforming TPR Crystallography Food Science Organic Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Condensed Matter Physics Food Science

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Oxy-Steam Reforming of Liquefied Natural Gas (LNG) on Mono- and Bimetallic (Ag, Pt, Pd or Ru)/Ni Catalysts

Ethanol Steam Reforming for Hydrogen Production over Bimetallic Pt–Ni/Al2O3

Effect of LaAlO$_{3}$-supported modified Ni-based catalysts on aqueous phase reforming of glycerol

Ir-Based Bimetallic Catalysts for Hydrogen Production through Glycerol Aqueous-Phase Reforming

Aqueous Phase Glycerol Reforming with Pt and PtMo Bimetallic Nanoparticle Catalysts: The Role of the Mo Promoter

Bimetallic Ni–Cu Catalysts for the Low-Temperature Ethanol Steam Reforming: Importance of Metal–Support Interactions

Hydrogen Production from Ethylene Glycol Aqueous Phase Reforming over Ni–Al Layered Hydrotalcite-Derived Catalysts

Decalin dehydrogenation on active carbon supported Pt-Ni bimetallic catalysts

Production of hydrogen over bimetallic Pt–Ni/δ-Al2O3: II. Indirect partial oxidation of LPG

Hydrogen production by aqueous phase reforming of sorbitol using bimetallic Ni–Pt catalysts: metal support interaction

Similar Documents

Oxy-Steam Reforming of Liquefied Natural Gas (LNG) on Mono- and Bimetallic (Ag, Pt, Pd or Ru)/Ni Catalysts

Ethanol Steam Reforming for Hydrogen Production over Bimetallic Pt–Ni/Al2O3

Effect of LaAlO$_{3}$-supported modified Ni-based catalysts on aqueous phase reforming of glycerol

Ir-Based Bimetallic Catalysts for Hydrogen Production through Glycerol Aqueous-Phase Reforming

Aqueous Phase Glycerol Reforming with Pt and PtMo Bimetallic Nanoparticle Catalysts: The Role of the Mo Promoter

Bimetallic Ni–Cu Catalysts for the Low-Temperature Ethanol Steam Reforming: Importance of Metal–Support Interactions

Hydrogen Production from Ethylene Glycol Aqueous Phase Reforming over Ni–Al Layered Hydrotalcite-Derived Catalysts

Decalin dehydrogenation on active carbon supported Pt-Ni bimetallic catalysts

Production of hydrogen over bimetallic Pt–Ni/δ-Al2O3: II. Indirect partial oxidation of LPG

Hydrogen production by aqueous phase reforming of sorbitol using bimetallic Ni–Pt catalysts: metal support interaction