NDLI: Carbon film covering originated from fullerene C$_{60}$ on the surface of lithium metal anode for lithium secondary batteries

Content Provider	Springer Nature Link
Author	Arie, Arenst Andreas Vovk, Oleg M. Song, Jin O. Cho, Byung Won Lee, Joong Kee
Copyright Year	2008
Abstract	Carbon films from fullerene C$_{60}$ were coated on the surface of lithium metal for the anode of lithium secondary battery. In order to investigate the relationship between the electrochemical characteristics of the carbon films and deposition technique, three different vacuum techniques were employed such as RF (radio frequency)—magnetron sputtering of C$_{60}$, plasma assisted thermal evaporation of C$_{60}$ and ion beam assisted thermal evaporation of fullerene C$_{60}$. From the physical and chemical characterization tests, we found that the carbon films produced by those above techniques mainly consist of sp$^{2}$/sp$^{3}$ hybridized amorphous carbons. Electrochemical tests implied that the cyclic performance was enhanced by the fullerene C$_{60}$ coating on lithium metal anode in comparison to the pure lithium metal one. This enhanced performance is due to the formation of thin carbon film on the surface of lithium metal anode which plays a role as a passive layer against the side reaction between lithium metal and the electrolyte.
Starting Page	248
Ending Page	253
Page Count	6
File Format	PDF
ISSN	13853449
Journal	Journal of Electroceramics
Volume Number	23
Issue Number	2-4
e-ISSN	15738663
Language	English
Publisher	Springer US
Publisher Date	2008-01-23
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Fullerene C$_{60}$ Vacuum deposition techniques Carbon films Anode Crystallography Electrochemistry Characterization and Evaluation of Materials Ceramics, Glass, Composites, Natural Methods Optical and Electronic Materials
Content Type	Text
Resource Type	Article
Subject	Ceramics and Composites Materials Chemistry Mechanics of Materials Condensed Matter Physics Electronic, Optical and Magnetic Materials Electrical and Electronic Engineering

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