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| Content Provider | Springer Nature Link |
|---|---|
| Author | Parra, R. Aldao, C. M. Varela, J. A. Castro, M. S. |
| Copyright Year | 2005 |
| Abstract | Variations on the microstructure development and on the electrical properties of SnO$_{2}$-based varistors are discussed on the basis of the oxygen vacancies created or annihilated by the presence of different additives. Electron paramagnetic resonance (EPR) analysis of sintered samples evidenced a substantial increase in the paramagnetic oxygen vacancies concentration when Nb$_{2}$O$_{5}$ is added to the SnO$_{2}$ ⋅ Co$_{3}$O$_{4}$ system. On the other hand, the observed diminution in the concentration of such species after the addition of Fe$_{2}$O$_{3}$ indicates solid solution formation. The quantification of paramagnetic oxygen vacancies allowed to confirm the proposed substitutions taking place in the lattice during sintering. These findings are supported by scanning electron microscopy, by density measurements and by current density versus electric field curves. The characterization of secondary phases through EDS assisted SEM and TEM is also reported in this work. |
| Starting Page | 149 |
| Ending Page | 156 |
| Page Count | 8 |
| File Format | |
| ISSN | 13853449 |
| Journal | Journal of Electroceramics |
| Volume Number | 14 |
| Issue Number | 2 |
| e-ISSN | 15738663 |
| Language | English |
| Publisher | Kluwer Academic Publishers |
| Publisher Date | 2005-01-01 |
| Publisher Place | Boston |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | defects electrical properties microstructure varistors EPR Polymer Sciences Optical and Electronic Materials Characterization and Evaluation Materials Ceramics, Glass, Composites, Natural Methods Crystallography |
| Content Type | Text |
| Resource Type | Article |
| Subject | Ceramics and Composites Materials Chemistry Mechanics of Materials Condensed Matter Physics Electronic, Optical and Magnetic Materials Electrical and Electronic Engineering |
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