NDLI: Piezoelectric properties of the high temperature MPB xPbTiO$_{3}$ - (1−x)[BiScO$_{3}$ + Bi(Ni$_{1/2}$Ti$_{1/2}$)O$

Content Provider	Springer Nature Link
Author	Ansell, Troy Y. Cann, David P.
Copyright Year	2013
Abstract	The ternary perovskite xPbTiO$_{3}$ - (1−x)[BiScO$_{3}$ + Bi(Ni$_{1/2}$Ti$_{1/2}$)O$_{3}$] (PT-BS-BNiT), where x = 0.54 is the morphotropic phase boundary composition, was studied for high temperature ferroelectric applications. Polycrystalline ceramics were prepared using the standard solid-state methods. The stoichiometric ceramic was found to have room temperature dielectric permittivity and loss values at 1 kHz of 1490 and 0.049 respectively. Piezoelectric properties, of the stoichiometric composition, measured included: P$_{r}$ = 31.0 μC/cm$^{2}$, E$_{c}$ = 25.0 kV/cm, d$_{33}$ = 340 pC/N, d$_{33}$ $^{*}$ = 896 pm/V, and a bipolar electromechanical strain of 0.25 %. From these data, the Curie temperature was T$_{C}$ = 370 °C and the depoling temperature was T$_{D}$ = 325 °C. Processing ceramics with excess bismuth improved the low field piezoelectric coefficients with a maximum of d33 = 445 pC/N, while increasing the lead content increased the transition temperatures. The depoling and Curie temperatures of all compositions were measured to be between 275 and 400 °C.
Starting Page	159
Ending Page	167
Page Count	9
File Format	PDF
ISSN	13853449
Journal	Journal of Electroceramics
Volume Number	31
Issue Number	1-2
e-ISSN	15738663
Language	English
Publisher	Springer US
Publisher Date	2013-06-29
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Piezoelectric Ferroelectric Perovskite Lead Ternary Optical and Electronic Materials Ceramics, Glass, Composites, Natural Methods Characterization and Evaluation of Materials Electrochemistry Crystallography
Content Type	Text
Resource Type	Article
Subject	Ceramics and Composites Materials Chemistry Mechanics of Materials Condensed Matter Physics Electronic, Optical and Magnetic Materials Electrical and Electronic Engineering

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