NDLI: Investigation of immiscible Sn–Zn coatings with two-layer microstructure as anode material for Li-ion battery

Content Provider	Springer Nature Link
Author	Du, Zhijia Zhang, Shichao Zhao, Jianfeng Fang, Yuan
Copyright Year	2012
Abstract	The exfoliation of Sn as a result of volume expansion led to the drastic capacity decay in lithium-ion batteries. In this article, the immiscible Sn–Zn coating was successfully prepared by electrodeposition and applied as the anode material in Li-ion batteries. The physical structure and electrochemical properties were characterized by X-ray diffraction, scanning electron microscope, electron probe microanalysis and charge–discharge test, respectively. The Sn–Zn deposit displayed unique two-layer morphology composed of a Zn flat bottom layer and a Sn dendritic upper layer. The novel Sn–Zn electrodes showed noticeable improvement in cyclability compared to pure Sn film. This improvement was assigned to the characteristic of the two-layer microstructure: the Zn interlayer enhanced the binding strength between Sn dendrites and copper foil; the abundant space among these individual Sn dendrites accommodated the volume expansion during lithiation process. The two-layer Sn–Zn coatings were anticipated as potential anode materials for Li-ion batteries.
Starting Page	477
Ending Page	482
Page Count	6
File Format	PDF
ISSN	0021891X
Journal	Journal of Applied Electrochemistry
Volume Number	42
Issue Number	7
e-ISSN	15728838
Language	English
Publisher	Springer Netherlands
Publisher Date	2012-05-05
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Li-ion batteries Anode materials Sn–Zn coatings Electrodeposition Physical Chemistry Industrial Chemistry/Chemical Engineering Electrochemistry
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Chemical Engineering Electrochemistry

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