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| Content Provider | Springer Nature Link |
|---|---|
| Author | Zaviska, François Drogui, Patrick Blais, Jean François Mercier, Guy |
| Copyright Year | 2009 |
| Abstract | This study examined the possibility to remove colour causing-compounds from synthetic effluent by indirect electrochemical oxidation using iridium oxide anode electrodes. Using a high concentration of chloride ions (17.1 mM) and various current densities, it was possible to produce high concentration of active chlorine with a specific production rate of 2.8 mg min$^{−1}$ A$^{−1}$. The best performance for acid methyl violet 2B dye (MV2B) decomposition was obtained using Ti/IrO$_{2}$ anodes operated at a current density of 15 mA cm$^{−2}$ during 40 min of treatment in the presence of 3.42 mM of chloride ions. Under these conditions, more than 99% of MV2B was removed (with a reaction rate apparent constant of 0.20 min$^{−1}$), whereas COD and TOC removal were 51% and 75%, respectively. The electrolytic cell was then used for the degradation of three other synthetic dye solutions: Eosin yellowish (EOY), Trypan Blue (TRB), Acridine Orange (ACO). TRB was the most difficult dye to remove from solution with a value reaction rate constant of 0.12 min$^{−1}$, compared to 0.19 min$^{−1}$ and 0.24 min$^{−1}$ recorded for ACO and EOY dyes, respectively. More than 99% of these dyes were removed by electrochemical oxidation. |
| Starting Page | 2397 |
| Ending Page | 2408 |
| Page Count | 12 |
| File Format | |
| ISSN | 0021891X |
| Journal | Journal of Applied Electrochemistry |
| Volume Number | 39 |
| Issue Number | 12 |
| e-ISSN | 15728838 |
| Language | English |
| Publisher | Springer Netherlands |
| Publisher Date | 2009-05-23 |
| Publisher Place | Dordrecht |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Active chlorine Indirect electrochemical oxidation Ti/IrO$_{2}$ anode Dye, Colour removal Industrial Chemistry/Chemical Engineering Physical Chemistry Electrochemistry |
| Content Type | Text |
| Resource Type | Article |
| Subject | Materials Chemistry Chemical Engineering Electrochemistry |
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