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| Content Provider | Springer Nature Link |
|---|---|
| Author | Wu, Chao Yan, Pengtao Zhang, Ruijun Jin, Jianglong Zhang, Xuesha Kang, Huimin |
| Copyright Year | 2015 |
| Abstract | Two carbide-derived carbons (CDCs) were synthesized by chlorination from TiC at 600 and 1000 °C. These CDCs were treated by HNO$_{3}$ solution and evaluated as supercapacitor electrode materials in an alkaline electrolyte. It is found that the structure in CDC synthesized at 600 °C is disordered carbon with micropores, whereas for the CDC synthesized at 1000 °C, the structure in it is mainly well-ordered graphitic structure with micro- and meso-pores. Due to the big difference of these two CDCs, HNO$_{3}$ activation plays the different effects in structure and consequently the specific capacitance. CDC synthesized at 600 °C is easier to be activated with the same HNO$_{3}$ concentration and the increase of specific capacitance with HNO$_{3}$ concentration mainly caused by pseudocapacitance. For CDC synthesized at 1000 °C, HNO$_{3}$ activation improves the wettability of it and the increased accessible surface area causes considerable increase in specific capacitance. |
| Starting Page | 849 |
| Ending Page | 856 |
| Page Count | 8 |
| File Format | |
| ISSN | 0021891X |
| Journal | Journal of Applied Electrochemistry |
| Volume Number | 45 |
| Issue Number | 8 |
| e-ISSN | 15728838 |
| Language | English |
| Publisher | Springer Netherlands |
| Publisher Date | 2015-05-09 |
| Publisher Place | Dordrecht |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Carbide-derived carbon Porous carbon Activation Supercapacitor Electrochemistry Physical Chemistry Industrial Chemistry/Chemical Engineering |
| Content Type | Text |
| Resource Type | Article |
| Subject | Materials Chemistry Chemical Engineering Electrochemistry |
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