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| Content Provider | Springer Nature Link |
|---|---|
| Author | Zhang, Jianlu Li, Liyu Nie, Zimin Chen, Baowei Vijayakumar, M. Kim, Soowhan Wang, Wei Schwenzer, Birgit Liu, Jun Yang, Zhenguo |
| Copyright Year | 2011 |
| Abstract | The stability of the electrolytes for all-vanadium redox flow battery was investigated with ex-situ heating/cooling treatment and in situ flow-battery testing methods. The effects of inorganic and organic additives have been studied. The additives containing the ions of potassium, phosphate, and polyphosphate are not suitable stabilizing agents because of their reactions with V(V) ions, forming precipitates of KVSO$_{6}$ or VOPO$_{4}$. Of the chemicals studied, polyacrylic acid and its mixture with CH$_{3}$SO$_{3}$H are the most promising stabilizing candidates which can stabilize all the four vanadium ions (V$^{2+}$, V$^{3+}$, VO$^{2+}$, and VO$_{2}$ $^{+}$) in electrolyte solutions up to 1.8 M. However, further effort is needed to obtain a stable electrolyte solution with >1.8 M V$^{5+}$ at temperatures higher than 40 °C. |
| Starting Page | 1215 |
| Ending Page | 1221 |
| Page Count | 7 |
| File Format | |
| ISSN | 0021891X |
| Journal | Journal of Applied Electrochemistry |
| Volume Number | 41 |
| Issue Number | 10 |
| e-ISSN | 15728838 |
| Language | English |
| Publisher | Springer Netherlands |
| Publisher Date | 2011-06-28 |
| Publisher Place | Dordrecht |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | All vanadium redox flow batteries Electrolyte stability Stabilizing agent Vanadium ions Energy storage Industrial Chemistry/Chemical Engineering Physical Chemistry Electrochemistry |
| Content Type | Text |
| Resource Type | Article |
| Subject | Materials Chemistry Chemical Engineering Electrochemistry |
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