NDLI: Subsolidus Phase Relations in the Systems M$_{2}$ $^{+}$O–M$^{2+}$O–V$_{2}$O$_{5}$(M$^{+}$ = Li, Na, K, Rb, Cs; M$^{2+}$ = Mg, Ca)

Content Provider	Springer Nature Link
Author	Slobodin, B. V. Surat, L. L.
Copyright Year	2004
Abstract	Subsolidus phase relations in the M$_{2}$O(M$_{2}$CO$_{3}$)–MgO–V$_{2}$O$_{5}$ and M$_{2}$O(M$_{2}$CO$_{3}$)–CaO–V$_{2}$O$_{5}$ (M = Li, Na, K, Rb, Cs) systems are studied. Twenty mixed vanadates are obtained, of which Rb$_{2}$CaV$_{2}$O$_{7}$ , Cs$_{2}$CaV$_{2}$O$_{7}$ , LiMg$_{4}$(VO$_{4}$)$_{3}$ , RbCaVO$_{4}$ , and CsCaVO$_{4}$ are identified for the first time. Structural data are summarized for all of the mixed vanadates: the space group and lattice parameters are indicated for 14 compounds (for 6 compounds, such data are obtained for the first time), and I and d data are presented for 8 compounds. Partial series of Ca$_{3}$(VO$_{4}$)$_{2}$-based solid solutions with the general formula Ca$_{3 – x }$M$_{2x }$(VO$_{4}$)$_{2}$ (M = Na, K, Rb, Cs) are identified in the range 0 < x ≤ 0.14. Six phase diagrams (M$^{+}$ = Li, Rb, Cs; M$^{2+}$ = Mg, Ca) are investigated and are compared with the phase diagrams of the other ternary systems in question. The key features of the ternary phase diagrams and, hence, the reactivity of the constituent oxides are shown to vary systematically in going from Li$_{2}$O to Cs$_{2}$O and from MgO to SrO, which is interpreted in terms of the variation in the ionic radius of the alkali and alkaline-earth metals.
Starting Page	188
Ending Page	194
Page Count	7
File Format	PDF
ISSN	00201685
Journal	Inorganic Materials
Volume Number	40
Issue Number	2
e-ISSN	16083172
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2004-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Inorganic Chemistry Industrial Chemistry/Chemical Engineering
Content Type	Text
Resource Type	Article
Subject	Materials Chemistry Metals and Alloys Chemical Engineering Inorganic Chemistry

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