NDLI: Chemical Cycle Kinetics: Removing the Limitation of Linearity of a Non-equilibrium Thermodynamic Description

Content Provider	Springer Nature Link
Author	Rubi, J. M. Bedeaux, D. Kjelstrup, S. Pagonabarraga, I.
Copyright Year	2013
Abstract	Chemical cycle kinetics is customarily analyzed by means of the law of mass action which describes how the concentrations of the substances vary with time. The connection of this approach with non-equilibrium thermodynamics (NET) has traditionally been restricted to the linear domain close to equilibrium in which the reaction rates are linear functions of the affinities. We show, by a pertinent formulation of the concept of local equilibrium in the mesoscopic description along the reaction coordinates, that the connection between kinetic and thermodynamic approaches is deeper than thought and holds in the nonlinear domain far from equilibrium, for higher values of the affinity. This new perspective indicates how to overcome the inherent limitation of classical NET in treating cyclic reactions, providing a description of closed and open cycles operating far from equilibrium, in accordance with thermodynamic principles. We propose that the new set of equations are tested and used for data reduction in chemical reaction kinetics.
Starting Page	1214
Ending Page	1228
Page Count	15
File Format	PDF
ISSN	0195928X
Journal	International Journal of Thermophysics
Volume Number	34
Issue Number	7
e-ISSN	15729567
Language	English
Publisher	Springer US
Publisher Date	2013-07-26
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Chemical kinetics Law of mass action Non-equilibrium thermodynamics Condensed Matter Physics Mechanics Industrial Chemistry/Chemical Engineering Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Condensed Matter Physics

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