NDLI: Equation of State for Nonpolar Fluid Mixtures: Prediction from Boiling Point Constants

Content Provider	Springer Nature Link
Author	Eslami, H.
Copyright Year	2001
Abstract	Our previous corresponding-states correlation for the second virial coefficient of nonpolar fluids, based on the normal boiling point parameters, has been employed to predict the equation of state of nonpolar fluid mixtures. The analytical equation of state is that of Ihm, Song, and Mason, which requires three temperature-dependent parameters, i.e., the second virial coefficient, a scaling constant for softness of repulsive forces, and a van der Waals covolume. In the previous work, we showed that the temperature-dependent parameters could be calculated by knowing the boiling point constants. In this work, it is shown that using a simple geometric mean for the boiling point temperature and an arithmetic mean for the liquid density at the normal boiling point is sufficient to determine the temperature-dependent parameters for mixtures. The equation of state has been utilized to calculate the liquid density of several nonpolar fluid mixtures. The agreement with experiment is good.
Starting Page	1781
Ending Page	1793
Page Count	13
File Format	PDF
ISSN	0195928X
Journal	International Journal of Thermophysics
Volume Number	22
Issue Number	6
e-ISSN	15729567
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2001-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Physical Chemistry Industrial Chemistry/Chemical Engineering Mechanics Condensed Matter
Content Type	Text
Resource Type	Article
Subject	Condensed Matter Physics

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