NDLI: The Effect of Impurities on the Evolution of the Melting Front Analyzed in a Two-Dimensional Representation for the Eutectic Pt

Content Provider	Springer Nature Link
Author	Castro, P. Bloembergen, P. Dong, W.
Copyright Year	2014
Abstract	The paper discusses the effect of two-front melting on the liquidus temperature of the eutectic Pt–C and the eutectic temperature of the system in its pure state. This influence factor has not been considered thus far in the uncertainty budget associated with the assignment of thermodynamic temperatures to the eutectics Co–C (1597.15 K), Pt–C (2011.05 K), and Re–C (2747.35 K), selected in the European Metrology Research Programme project Implementing the New Kelvin. For Pt–C, simulation of the effect of two-front melting on the melting process has been done before in a 1D analytical model, and this formed the starting point to the present study. In this study the melting process is analyzed by means of a 2D axisymmetrical finite-volume model. In the model, freezing and melting are considered for an impure ingot and for a pure ingot. As to the impure ingot, the impurity concentrations are the concentrations met in current practice of the realization of the high-temperature reference fixed point, but formulated in terms of an effective concentration and associated effective distribution coefficient $$k< 1$$ , related to a Scheil fit to the melting curve at given melting conditions as measured for the eutectic Pt–C. Heat injection rates for melting varied from 15 000 W $${\cdot }$$ m $$^{-2}$$ down to 3000 W $${\cdot }$$ m $$^{-2}$$ . In any case for the impure system, two melting fronts are showing up. For the pure system, only one melting front is generated, traveling from the outside of the ingot toward its inside.
Starting Page	1378
Ending Page	1390
Page Count	13
File Format	PDF
ISSN	0195928X
Journal	International Journal of Thermophysics
Volume Number	35
Issue Number	6-7
e-ISSN	15729567
Language	English
Publisher	Springer US
Publisher Date	2014-08-08
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	High-temperature fixed point Impurity distribution Melting front Condensed Matter Physics Mechanics Industrial Chemistry/Chemical Engineering Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Condensed Matter Physics

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