NDLI: Predicting the virial coefficients and thermodynamic properties of a multicomponent mixture with application to the ternary mixture of CH$_{2}$F$_{2}$+CF$_{3}$CHF$_{2}$+CF$_{3}$CH$

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Predicting the virial coefficients and thermodynamic properties of a multicomponent mixture with application to the ternary mixture of CH$_{2}$F$_{2}$+CF$_{3}$CHF$_{2}$+CF$_{3}$CH$_{2}$F

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Predicting the virial coefficients and thermodynamic properties of a multicomponent mixture with application to the ternary mixture of CH$_{2}$F$_{2}$+CF$_{3}$CHF$_{2}$+CF$_{3}$CH$_{2}$F

Content Provider	Springer Nature Link
Author	Weber, L. A.
Copyright Year	1997
Abstract	A model for estimating second and third virial coefficients, which has been used successfully to represent the behavior of pure gases and binary mixtures, was applied to a ternary mixture. An estimate for the ternary third virial coefficient.C $_{123}$, was added to the model. Three experimentally determined binary interaction parameters were also used. The model has been applied to the ternary mixture CH$_{2}$F$_{2}$+CF$_{3}$CHF$_{2}$+CF$_{3}$CH$_{2}$F (R32+R125+R134a). The results are useful for calculating gas-phase densities, thermodynamic properties, and fugacities for phase equilibrium calculations. The use of such models leads to a considerable economy of effort in the case of multicomponent mixtures. Examples of the thermodynamic properties are given for the equimolar ternary mixture in the range from the dew-point temperature to 400 K at pressures of 0.5, 1, and 2 MPa. Calculated densities and speeds of sound are compared with new experimental values for a near-equimolar composition.
Starting Page	161
Ending Page	172
Page Count	12
File Format	PDF
ISSN	0195928X
Journal	International Journal of Thermophysics
Volume Number	18
Issue Number	1
e-ISSN	15729567
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	1997-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	density R134a R32 R125 refrigerants ternary mixture thermodynamic properties virial coefficients Physical Chemistry Industrial Chemistry/Chemical Engineering Mechanics Condensed Matter
Content Type	Text
Resource Type	Article
Subject	Condensed Matter Physics

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Thermodynamic properties of seven gaseous halogenated hydrocarbons from acoustic measurements: CHClFCF$_{3}$, CHF$_{2}$ CF$_{3}$, CF$_{3}$ CH$_{3}$, CHF$_{2}$CH$_{3}$, CF$_{3}$CHFCHF$_{2}$, CF$_{3}$CH$_{2}$CF$_{3}$, and CHF$_{2}$CF$_{2}$CH$_{2}$F

Equation of state and ideals-gas heat capacity of a gaseous mixture of 1,1,1,2-tetrafluoroethane, pentafluoroethane, and difluoromethane

Liquid Thermal Conductivity of Ternary Mixtures of Difluoromethane (R32), Pentafluoroethane (R125), and 1,1,1,2-Tetrafluoroethane (R134a)$^{1}$

Viscosity of R134a, R32, And R125 at Saturation

Burnett Measurements and Virial Coefficients for the R32 + N$_{2}$O System

Thermophysical Properties of Gaseous CF$_{4}$ and C$_{2}$F$_{6}$ from Speed-of-Sound Measurements

The Thermal Diffusivity of the Refrigerants R32, R125, and R143a

DOI:10.1068/htwu135 Temperature and concentration dependences of surface tension of binary mixtures of ozone-safe refrigerants (1999)

Equations of State for the Ozone-Safe Refrigerants R32 and R125

Predicting the virial coefficients and thermodynamic properties of a multicomponent mixture with application to the ternary mixture of CH$_{2}$F$_{2}$+CF$_{3}$CHF$_{2}$+CF$_{3}$CH$_{2}$F

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