NDLI: Thermodynamics of multicomponent mixtures near the liquid-vapor critical point

Content Provider	Springer Nature Link
Author	Belyakov, M. Yu. Vorov, V. P. Gorodetskii, E. E. Grigor’ev, B. A. Deshabo, V. A. Kosov, V. I. Kulikov, V. D. Kur’yakov, V. N. Yudin, I. K. Yudin, D. I.
Copyright Year	2012
Abstract	A general approach based on parameterization of physical properties by two scaling functions is proposed to describe the physical properties of multicomponent mixtures in the vicinity of critical points. The present approach allows us to obtain explicit expressions for anomalous parts of various thermodynamic parameters. The temperature dependencies of pressure, of the isochoric heat capacity C ρ, x , and of the intensity of scattered light were measured near the liquid-vapor critical point of a three-component mixture, methane-0.35 mol propane-0.15 mol pentane. P-T measurements were carried out at 10 isochores for densities 0.185–0.444 g/cm3. Measurements of C ρ, x and the intensity of light scattering were carried out at 4 and 3 near-critical isochores, respectively. Comparison of the experimental data and theoretical calculations showed that the present approach provides a quantitative description of the experimental data, and thereby, the complete equation of state of the studied system was derived.
Starting Page	479
Ending Page	487
Page Count	9
File Format	PDF
ISSN	0018151X
Journal	High Temperature
Volume Number	50
Issue Number	4
e-ISSN	16083156
Language	English
Publisher	SP MAIK Nauka/Interperiodica
Publisher Date	2012-08-15
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Physical Chemistry Materials Science Classical Continuum Physics Atoms and Molecules in Strong Fields, Laser Matter Interaction Industrial Chemistry/Chemical Engineering
Content Type	Text
Resource Type	Article
Subject	Engineering Condensed Matter Physics

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