NDLI: Two-Photon Photochemical Reactions of Aromatic Compounds in the Gas Phase

Content Provider	Springer Nature Link
Author	Potapov, V. K. Matyuk, V. M.
Copyright Year	2001
Abstract	Studies on the gas-phase two-photon photochemistry of aromatic compounds performed in the past 25 years were summarized. Photophysical and photochemical unimolecular and bimolecular reactions occurring in the gas phase on the exposure of molecular systems (aliphatic aldehydes, ketones, and alcohols; aromatic hydrocarbons and their halogen derivatives; and heteroaromatic compounds with a conjugated π-electron system) to pulsed laser UV radiation were considered. Data on the kinetics and mechanisms of primary two-photon photoexcitation, photodissociation, and photoionization of aromatic molecules were systematized, and the nature of electronically excited states responsible for these processes was determined. Data on the reactivity of transient species and on the kinetics of elementary steps of laser UV photolysis (bimolecular charge transfer and heavy particle transfer reactions and termolecular association and cluster ion formation reactions) were presented. General prerequisites to the stability of aromatic compounds under non-steady-state conditions of UV photolysis were found in accordance with the electronic structure of reactants and with the donor–acceptor properties of mixture components.
Starting Page	90
Ending Page	99
Page Count	10
File Format	PDF
ISSN	00181439
Journal	High Energy Chemistry
Volume Number	35
Issue Number	2
e-ISSN	16083148
Language	English
Publisher	Kluwer Academic Publishers-Plenum Publishers
Publisher Date	2001-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Physical and Theoretical Chemistry

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