NDLI: Simulation of the thermodynamic properties of glass-forming melts in the Na2O-B2O3-SiO2 system in the framework of the generalized lattice theory of associated solutions

Content Provider	Springer Nature Link
Author	Plotnikov, E. N. Stolyarova, V. L.
Copyright Year	2006
Abstract	The possibility of calculating the thermodynamic properties of melts in the Na2O-B2O3-SiO2 system (as in the previously studied Cs2O-B2O3-SiO2 system) formed by two glass-former oxides (B2O3, SiO2) and one modifier oxide (Na2O) with the use of the vacancy variant of the generalized lattice theory of associated solutions is demonstrated. A comparison with the experimental thermodynamic functions previously determined by the electromotive force method and high-temperature mass spectrometry at temperatures of 1200, 1273, and 1350 K shows that the calculations performed within this approach lead to reliable thermodynamic functions. It is noted that the proposed model ignores the change in the coordination number of boron atoms to four and the possibility of forming associates in melts of compositions lying in the metastable phase separation region at temperatures higher than the phase separation temperature.
Starting Page	422
Ending Page	435
Page Count	14
File Format	PDF
ISSN	10876596
Journal	Glass Physics and Chemistry
Volume Number	32
Issue Number	4
e-ISSN	1608313X
Language	English
Publisher	Nauka/Interperiodica
Publisher Date	2006-01-01
Publisher Place	Moscow
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Physical Chemistry Materials Science Characterization and Evaluation Materials Ceramics, Glass, Composites, Natural Methods
Content Type	Text
Resource Type	Article
Subject	Ceramics and Composites Materials Chemistry Condensed Matter Physics

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Calculations of the Thermodynamic Properties of Glasses and Melts in the Na2O-SiO2 and B2O3-SiO2 Systems on the Basis of the Generalized Lattice Theory of Associated Solutions

Calculations of the thermodynamic properties of glasses and melts in the Cs2O-B2O3-SiO2 system in the framework of the generalized lattice theory of associated solutions

Vaporization and Thermodynamic Properties of Melts in the Na2O–B2O3–SiO2 System

Thermodynamic properties of melts in the SrO-SiO2 system from data of the generalized lattice theory of associated solutions

Analysis of regularities in composition dependence of the viscosity for glass-forming oxide melts: I. viscosity of melts in the Na2O-RO-SiO2 and Na2O-R2O-SiO2 systems

Migration processes in the glass forming melts of the Na2O–BaO–Ga2O3–SiO2 system

Mass spectrometric investigation of the thermodynamic properties of glass melts in the Cs2O-B2O3-SiO2 system at high temperatures

Physicochemical properties of glasses of the Na2O-B2O3-SiO2-Fe2O3 system in the 8Na2O/70SiO2 section

Simulation of the thermodynamic properties of glass melts in the Cs2O-B2O3-SiO2 system in the concentration range 0.06–0.50 mole fractions of Cs2O at a temperature of 1020 K

Simulation of the thermodynamic properties of glass-forming melts in the Na2O-B2O3-SiO2 system in the framework of the generalized lattice theory of associated solutions

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