NDLI: Correlation between atomic structure, structural nanoinhomogeneity, and quadratic optical nonlinearity in glasses of the K2O-TiO2-P2O5 system

Content Provider	Springer Nature Link
Author	Sigaev, V. N. Lotarev, S. V. Sarkisov, P. D. Smelyanskaya, É. N. Akimova, O. V. Stefavich, S. Yu. Champagn, B. Wagner, D. Volkov, A. A. Komandin, G. A. Koltashev, V. V. Plotnichenko, V. G. Pernice, P. Aronne, A.
Copyright Year	2006
Abstract	The methods of small angle synchrotron radiation scattering, vibration spectroscopy, and second harmonic generation are applied to glasses of the K2O-TiO2-P2O5 system near the stoichiometry of potassium titanyl-phosphate to demonstrate that at the initial stage of phase separation, while glass remains x-ray amorphous and clear, it can possess quadratic optical nonlinearity. The emergence of nonlinearity is facilitated by the formation of nanoheterogeneities in glass whose structure resembles the structural pattern of a nonlinear-optical crystal. Acorrelation established between the structural specifics of x-ray amorphous glass and its quadratic optical nonlinearly suggests the advisability of describing the short-range and medium-range orders of glasses at the glass-formation boundary in the context of quasicrystallite models.
Starting Page	7
Ending Page	11
Page Count	5
File Format	PDF
ISSN	03617610
Journal	Glass and Ceramics
Volume Number	63
Issue Number	1-2
e-ISSN	15738515
Language	English
Publisher	Kluwer Academic Publishers-Consultants Bureau
Publisher Date	2006-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Materials Science Characterization and Evaluation Materials Ceramics, Glass, Composites, Natural Methods
Content Type	Text
Resource Type	Article
Subject	Ceramics and Composites Materials Chemistry Mechanics of Materials

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