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| Content Provider | Springer Nature Link |
|---|---|
| Author | Pagni, Richard M. |
| Copyright Year | 2011 |
| Abstract | Primary and methyl aliphatic halides and tosylates undergo substitution reactions with nucleophiles in one step by the classic SN2 mechanism, which is characterized by second-order kinetics and inversion of configuration at the reaction center. Tertiary aliphatic halides and tosylates undergo substitution reactions with nucleophiles in two (or more) steps by the classic SN1 mechanism, which is characterized by first-order kinetics and incomplete inversion of configuration at the reaction center due to the presence of ion pairs. When the nucleophile is also the solvent, the substitution reaction is called a solvolysis, and both the SN2 and SN1 reactions now obey first-order kinetics. Schleyer and Bentley have provided solid, but not conclusive, evidence that secondary substrates undergo solvolysis by a merged mechanism, one that blends characteristics of both the SN2 and SN1 mechanisms. The following paper presents the history of their sustained pursuit of a merged mechanism and subsequent rebuttals to this claim. Several issues related to the philosophy and sociology of science are also discussed. |
| Starting Page | 131 |
| Ending Page | 143 |
| Page Count | 13 |
| File Format | |
| ISSN | 13864238 |
| Journal | Foundations of Chemistry |
| Volume Number | 13 |
| Issue Number | 2 |
| e-ISSN | 15728463 |
| Language | English |
| Publisher | Springer Netherlands |
| Publisher Date | 2011-07-09 |
| Publisher Place | Dordrecht |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Solvolysis reaction SN1 reaction SN2 reaction Two-step mechanism One-step mechanism Ion pairing Merged mechanism Solvent ionizing power Solvent nucleophilicity 2-Adamantyl substrates Kinetics α secondary isotope effects substrates Nucleophilic solvent assistance SN2 (intermediate) Physical Chemistry Philosophy of Science History Chemistry/Food Science |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry History Biochemistry |
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