NDLI: Determination and estimation of partitioning properties for substituted phosphates and thiophosphates

Content Provider	Springer Nature Link
Author	Yuying, Dong Guanghui, Ding Ying, Cao Zhuang, Wang Cheng, Sun
Copyright Year	2008
Abstract	Substituted phenylglyoxylonitrile oximino phosphates and thiophosphates invested as a synergist of molluscicide killing snail eggs have been exposed to the environment with very little attention. The partitioning properties, aqueous solubility (S w), n-octanol–water partition coefficient (K ow) and soil organic carbon sorption coefficients (K oc) of 16 O, O′-dialkyl, O″-(substituted phenylglyoxylonitrile oximino) phosphates and thiophosphates, were determined by the traditional shaking flask method. The parameters of molecular fragment connectivity indices (MFCIs) and linear solvation energy relationships (LSERs) were used as molecular descriptors to establish a series of correlation equations successfully. The obtained correlation equations provided a quantitative method to predict the three partitioning properties for new exploited substituted phosphates and thiophosphates. More valuable, the successful application of MFCIs provides us with a good example and a good idea to improve traditional molecular connectivity indices (MCIs).
Starting Page	443
Ending Page	450
Page Count	8
File Format	PDF
ISSN	01676369
Journal	Environmental Monitoring and Assessment
Volume Number	152
Issue Number	1-4
e-ISSN	15732959
Language	English
Publisher	Springer Netherlands
Publisher Date	2008-05-23
Publisher Place	Dordrecht
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Determination Estimation Partitioning properties Substituted phosphates and thiophosphates MFCIs LSERs Environmental Monitoring/Analysis Environmental Management Ecotoxicology Atmospheric Protection/Air Quality Control/Air Pollution Ecology
Content Type	Text
Resource Type	Article
Subject	Pollution Medicine Management, Monitoring, Policy and Law

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