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| Content Provider | Springer Nature Link |
|---|---|
| Author | Huan, Zhibo Luo, Jinhui Xu, Zhi Xie, Defang |
| Copyright Year | 2015 |
| Abstract | The dissipation and residues of an eco-friendly bio-pesticide, spinosad, in cowpea under field conditions were studied using ultra-performance liquid chromatography with tandem mass spectrometry (UPLC-MSMS) after Quick, Easy, Cheap, Effective, Rugged, and Safe (QuEChERS) extraction. The method exhibited good linearity with respect to spinosyn A and spinosyn D in solvent or blank cowpea matrix with correlation coefficients >0.99. Additionally, matrix effects were not significant in the range 0.987–1.014, and the average recoveries at three concentration levels were 75.1–91.1 and 79.4–90.5 % for spinosyn A and spinosyn D, respectively. The intra- and inter-day relative standard deviations were 2.5–9.3 and 7.8–9.8 % for spinosyn A, respectively, and 4.1–7.9 and 6.6–8.3 % for spinosyn D, respectively. The limits of detection (LODs) and limits of quantification (LOQs) were 0.005 and 0.01 mg kg−1, respectively, for spinosyn A, and 0.002 and 0.005 mg kg−1, respectively, for spinosyn D. The dissipation of spinosad (sum of spinosyn A and spinosyn D) fitted well to first-order kinetics with half-lives of 0.9–1.5 days. The highest residue (HR) at pre-harvest interval (PHI) of 12 h was 0.321 mg kg−1. Compared with the maximum residue limit (MRL) set by Codex, a PHI of at least 24 h was recommended. The estimated daily chronic intake of spinosad from cowpea was less than 0.14 % of the acceptable daily intake (ADI). Therefore, the risk of consuming cowpea sprayed with spinosad under recommended field conditions was considered acceptable for the Chinese population. |
| Starting Page | 1 |
| Ending Page | 8 |
| Page Count | 8 |
| File Format | |
| ISSN | 01676369 |
| Journal | Environmental Monitoring and Assessment |
| Volume Number | 187 |
| Issue Number | 11 |
| e-ISSN | 15732959 |
| Language | English |
| Publisher | Springer International Publishing |
| Publisher Date | 2015-10-27 |
| Publisher Place | Cham |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Spinosad Dissipation Crop residues Risk assessment Cowpea UPLC-MSMS Environmental Monitoring/Analysis Environmental Management Ecotoxicology Atmospheric Protection/Air Quality Control/Air Pollution Ecology |
| Content Type | Text |
| Resource Type | Article |
| Subject | Pollution Medicine Management, Monitoring, Policy and Law |
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