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  1. Chemistry of Heterocyclic Compounds
  2. Chemistry of Heterocyclic Compounds : Volume 36
  3. Chemistry of Heterocyclic Compounds : Volume 36, Issue 5, May 2000
  4. E-β-Styrylgermatrane
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Chemistry of Heterocyclic Compounds : Volume 53
Chemistry of Heterocyclic Compounds : Volume 52
Chemistry of Heterocyclic Compounds : Volume 51
Chemistry of Heterocyclic Compounds : Volume 50
Chemistry of Heterocyclic Compounds : Volume 49
Chemistry of Heterocyclic Compounds : Volume 48
Chemistry of Heterocyclic Compounds : Volume 47
Chemistry of Heterocyclic Compounds : Volume 46
Chemistry of Heterocyclic Compounds : Volume 45
Chemistry of Heterocyclic Compounds : Volume 44
Chemistry of Heterocyclic Compounds : Volume 43
Chemistry of Heterocyclic Compounds : Volume 42
Chemistry of Heterocyclic Compounds : Volume 41
Chemistry of Heterocyclic Compounds : Volume 40
Chemistry of Heterocyclic Compounds : Volume 39
Chemistry of Heterocyclic Compounds : Volume 38
Chemistry of Heterocyclic Compounds : Volume 37
Chemistry of Heterocyclic Compounds : Volume 36
Chemistry of Heterocyclic Compounds : Volume 36, Issue 12, December 2000
Chemistry of Heterocyclic Compounds : Volume 36, Issue 11, November 2000
Chemistry of Heterocyclic Compounds : Volume 36, Issue 10, October 2000
Chemistry of Heterocyclic Compounds : Volume 36, Issue 9, September 2000
Chemistry of Heterocyclic Compounds : Volume 36, Issue 8, August 2000
Chemistry of Heterocyclic Compounds : Volume 36, Issue 7, July 2000
Chemistry of Heterocyclic Compounds : Volume 36, Issue 6, June 2000
Chemistry of Heterocyclic Compounds : Volume 36, Issue 5, May 2000
Cyclic azomethines and their hydrogenated derivatives. (Review)
Effects of chelation on the interaction of substituted 3-hetaryl-4-thioxochromones with lanthanide shift reagents
Alkaline scission of a urea unit in 5-alkyl-2-amino-N-ureido-3,4-dicyanopyrroles
Synthesis of substituted 5H-1,2,3,4,6,7,8,9-octahydrodipyrido-[4,3-b;3′,4′-d]pyrroles by the Pictet-Spengler condensation
Synthesis of tryptamines containing a sulfo group in the benzene ring
Synthesis of (S)-proline derivatives with an alkylated N-benzyl substituent. Benzylation of (S)-indoline-2-carboxylic acid
Synthesis of 13,15-pyrazoloprostanoids
Acylation of 1-arylpyrazolidin-3-ones
Improved method for the preparation of 3-aryl- and 3-styrylimidazo[1,5-a]pyridines
Condensed isoquinolines. 9. Alkylation of 7,12-dihydro-5H-isoquino[2,3-a]quinazolin-5-ones
Reaction of aminoquinolines with unsaturated carboxylic acids. 2. Cyclization of N-quinolyl-β-alanines
Synthesis and structure of 2-methyl-6-oxo-7,8-dihydrospiro(benzo[h]-triazolo[3,4-b]quinazoline-7,1′-cyclopentane)
Synthesis of 2,3-disubstituted 4-oxo-3,4,5,6-tetrahydrospiro-(benzo[h]quinazoline-5,1′-cyclopentanes)
Products from heterodiene synthesis and 1,3-cycloaddition in the reaction of N,N-disubstituted 2-aminooxazoles with maleimide
Synthesis and heterocyclization of dithiocarbamoylacetoacetic esters and anilides
Salts of 2,5-dimercapto-1,3,4-thiadiazole
E-β-Styrylgermatrane
Synthesis of 2-alkylthio-4′-oxo-5,5-pentamethylenespiro-[1-pyrroline-3,1′-cyclohexadienes]
Study of the orientation of the Thorpe-Ziegler reaction
Formation and cleavage of the quinazolinium ring in Vilsmeier-Haack formylation of 4-dialkylamino-substituted naphthalic acid derivatives
Activation of the Kost-Sagitullin rearrangement in a series of 2-benzylpyrimidine derivatives
A second type of stabilization of alkoxycarbonyl(imidoyl)ketenes
Unusual reaction of condensed 2,3-dihydro-2,3-pyrrolediones witho-phenylenediamine
4,6-dihydrofuro[3,4-d]imidazole: A new heterocyclic system
Regioselective addition of styrene to 4,5-dihydro-5-methyl-3H-spiro-[2-benzazepine-3,1′-cyclohexane] N-oxide
Heterocyclization in Vilsmeier-Haack formylation of dimethylamino-substituted 2,5-diaryloxazoles and 2,5-diaryl-1,3,4-oxadiazoles
A convenient approach to synthesis of 1,2,3-triazole-4-carbothioamides
Chemistry of Heterocyclic Compounds : Volume 36, Issue 4, April 2000
Chemistry of Heterocyclic Compounds : Volume 36, Issue 3, March 2000
Chemistry of Heterocyclic Compounds : Volume 36, Issue 2, February 2000
Chemistry of Heterocyclic Compounds : Volume 36, Issue 1, January 2000
Chemistry of Heterocyclic Compounds : Volume 35
Chemistry of Heterocyclic Compounds : Volume 34
Chemistry of Heterocyclic Compounds : Volume 33

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E-β-Styrylgermatrane

Content Provider Springer Nature Link
Author Ignatovich, L. Belyakov, S. Popelis, Yu. Lukevics, E.
Copyright Year 2000
Abstract E-β-1-(2-Phenylethenyl)-2,8,9-trioxa-5-aza-1-germatricyclo[3.3.3.01,5]undecane (β-Styrylgermatrane) was obtained as the result of sequential reactions: the introduction of germanium dibromide at the C−Br bond of β-bromostyrene and the alcoholysis of tribromogermane to the triethoxy derivative with subsequent transetherification by triethanolamine. The structure ofβ-Styrylgermatrane and 2.215 Å length of the transannular N→Ge bond were established by the method of NMR and X-ray diffraction analysis. It was found that the introduction of the CH=CH portion between the aromatic ring and the atrane grouping lowers the toxicity of the compound by the factor of 40.
Starting Page 603
Ending Page 606
Page Count 4
File Format PDF
ISSN 00093122
Journal Chemistry of Heterocyclic Compounds
Volume Number 36
Issue Number 5
e-ISSN 15738353
Language English
Publisher Kluwer Academic Publishers-Plenum Publishers
Publisher Date 2000-01-01
Publisher Place New York
Access Restriction One Nation One Subscription (ONOS)
Subject Keyword germatrane molecular structure toxicity Organic Chemistry Pharmacy
Content Type Text
Resource Type Article
Subject Organic Chemistry
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