NDLI: On the nature of the burning rate-controlling reaction of energetic materials for the gas-phase model

Content Provider	Springer Nature Link
Author	Sinditskii, V. P.
Copyright Year	2007
Abstract	For model systems with known kinetics of elementary reactions (CH3NO2 and HN3), temperature ranges are established in which the rate-controlling reactions are the initial endothermic decomposition of the starting material or the subsequent secondary reactions. Heat release in reactions of NO2, NO, and N2O with various fuels, such as CH2O, CO, H2, and HCN, is modeled to establish the kinetic parameters and nature of the rate-controlling reactions in gas flames of nitro compounds. It is shown that the activation energy of the heat-release reaction due to the interaction of NO2 with a hydrocarbon fuel (which is characteristic of the first flame of nitro compounds) is in the range of 29–33 kcal/mole, depending on the type of fuel. According to the calculations performed, the activation energy of the rate-controlling heat-releasing process due to the deoxidation of NO and N2O (which is typical of the second flame of nitro compounds) is 43–58 kcal/mole. In the range of high pressures, where the flames merge, the kinetic parameters of heat release are determined by the reactions of the most reactive nitrogen oxide NO2.
Starting Page	297
Ending Page	308
Page Count	12
File Format	PDF
ISSN	00105082
Journal	Combustion, Explosion and Shock Waves
Volume Number	43
Issue Number	3
e-ISSN	15738345
Language	English
Publisher	Kluwer Academic Publishers-Consultants Bureau
Publisher Date	2007-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	energetic materials nitromethane hydrazoic acid combustion kinetic mechanism Mechanics Mechanics, Fluids, Thermodynamics Physical Chemistry Vibration, Dynamical Systems, Control Engineering
Content Type	Text
Resource Type	Article
Subject	Chemistry Physics and Astronomy Fuel Technology Chemical Engineering Energy Engineering and Power Technology

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