NDLI: Novel Ultrahigh-Energy Materials

Content Provider	Springer Nature Link
Author	Talawar, M. B. Sivabalan, R. Asthana, S. N. Singh, H.
Copyright Year	2005
Abstract	This paper reviews the recent work carried out in the field of modern high-energy materials (HEMs) with the emphasis on homoleptic polynitrogen compounds. A large volume of quantum-chemical investigations have predicted the possibility of existence of polynitrogen compounds not only as short-lived transient species but also in the form of isolable discrete molecules. Despite the theoretical speculations, only a few polynitrogen ions are known today in addition to well-entrenched N 1− 3 discovered almost 100 year ago. Extraordinary potential of these green molecules to deliver high amounts of energy in comparison with today’s and tomorrow’s most powerful HEMs, namely, hexanitrohexaazaisowurtzitane (CL-20) and octanitrocubane (ONC), has fuelled the imagination of propellant and explosive engineers and technologists. Research activities are in progress in many quantum-chemical schools to explore the possibility of other promising polynitrogen compounds. After the recent discovery of key synthons/building blocks Mg(N5)2, N 1+ 5 SbF 1− 6 , N 1+ 5 SbF11, N 1+ 5 , N 1+ 5 SnF6, and N 1+ 5 Sn(CF3)4, the wealth of polynitrogen compounds is just waiting to be harvested by the HEMs community. There are ambitious plans all over the globe to realize N60, which only prove a eco-friendly dense powerhouse of energy.
Starting Page	264
Ending Page	277
Page Count	14
File Format	PDF
ISSN	00105082
Journal	Combustion, Explosion and Shock Waves
Volume Number	41
Issue Number	3
e-ISSN	15738345
Language	English
Publisher	Kluwer Academic Publishers-Consultants Bureau
Publisher Date	2005-01-01
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	polynitrogen high-energy materials Physical Chemistry Mechanics, Fluids, Thermodynamics Mechanics Engineering Vibration, Dynamical Systems, Control
Content Type	Text
Resource Type	Article
Subject	Chemistry Physics and Astronomy Fuel Technology Chemical Engineering Energy Engineering and Power Technology

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1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
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