NDLI: Thermal explosion in a binary homogeneous mixture

Content Provider	Springer Nature Link
Author	Filimov, V. Yu. Koshelev, K. B.
Copyright Year	2015
Abstract	Self-heating processes in binary homogeneous mixtures are studied based on the analysis of phase trajectories on the heating rate–temperature plane. The proposed approach allows determining the characteristic regions of exothermic reactions in the parametric diagram of the Todes criterion versus the Semenov criterion. Generalized strict criteria for the degeneration of thermal explosion are determined for reactions with low activation energy and reactions with a low thermal effect for any reaction orders. An approximating formula describing the dependence of the Todes criterion on the Semenov criterion is derived for calculating the critical conditions of thermal explosion up to its complete degeneration for reaction orders higher (or equal to) one. A criterion for the applicability of the classical thermal explosion theory as a special case of the proposed model is found. A diagram of the critical parameters in the introduced new variables is considered to predict and control the self-heating kinetics of mixtures.
Starting Page	644
Ending Page	655
Page Count	12
File Format	PDF
ISSN	00105082
Journal	Combustion, Explosion and Shock Waves
Volume Number	51
Issue Number	6
e-ISSN	15738345
Language	English
Publisher	Pleiades Publishing
Publisher Date	2015-12-15
Publisher Place	Moscow
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	self-heating phase trajectories thermal explosion binary mixtures degeneration critical conditions Mechanics Classical Continuum Physics Physical Chemistry Vibration, Dynamical Systems, Control Engineering
Content Type	Text
Resource Type	Article
Subject	Chemistry Physics and Astronomy Fuel Technology Chemical Engineering Energy Engineering and Power Technology

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