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| Content Provider | Springer Nature Link |
|---|---|
| Author | Budiman, Anatta Wahyu Nam, Ji Su Park, Jae Hyun Mukti, Ryan Indra Chang, Tae Sun Bae, Jong Wook Choi, Myoung Jae |
| Copyright Year | 2016 |
| Abstract | Acetic acid (AA) has been largely used with a wide range of applications such as a raw material for a synthesis of vinyl acetate monomer, cellulose acetate or acetate anhydrate, acetate ester and a solvent for a synthesis of terephthalic acid and so on. The present paper briefly summarizes the commercialized chemical processes with their Rh or Ir-based catalytic systems in a liquid-phase carbonylation reaction such as Monsanto, Cativa and Acetica processes. In addition, some alternative catalytic systems such as heterogeneous catalysts to produce AA by direct oxidation or indirect carbonylation of dimethyl ether through BP-SaaBre process in a gas-phase reaction to solve some problems such as a difficult separation of homogeneous catalysts in a corrosive reaction medium. Some home-made heterogeneous catalysts such as a rhodium incorporated graphitic carbon nitride (Rh-g-C3N4) and some heterogenized homogeneous catalysts using the supports of tungsten carbide, iron oxide or graphitic carbon nitride containing rhodium complexes were also introduced for the synthesis of AA through a liquid-phase methanol carbonylation reaction to effectively solve the leaching problem of active rhodium metal as well as to mitigate the separation problem of homogeneous catalysts. |
| Starting Page | 173 |
| Ending Page | 193 |
| Page Count | 21 |
| File Format | |
| ISSN | 15711013 |
| Journal | Catalysis Surveys from Asia |
| Volume Number | 20 |
| Issue Number | 3 |
| e-ISSN | 15749266 |
| Language | English |
| Publisher | Springer US |
| Publisher Date | 2016-06-21 |
| Publisher Place | New York |
| Access Restriction | One Nation One Subscription (ONOS) |
| Subject Keyword | Acetic acid Methanol carbonylation Heterogeneous catalysts Heterogenized homogeneous catalysts Graphitic carbon nitride Catalysis Physical Chemistry Industrial Chemistry/Chemical Engineering Characterization and Evaluation of Materials |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Catalysis |
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