NDLI: Metal Phosphides: Preparation, Characterization and Catalytic Reactivity

Content Provider	Springer Nature Link
Author	Prins, Roel Bussell, Mark E.
Copyright Year	2012
Abstract	The preparation, characterization, and catalytic activity of supported metal phosphides are reviewed. Reduction of metal compounds together with phosphate is a convenient method to prepare metal phosphides, but requires high temperature. Reduction with phosphite, hypophosphite, or phosphine and the plasma reduction of phosphate can be carried out at lower temperatures, which leads to smaller metal phosphide particles and more active catalysts. Organometallic routes allow the separate synthesis of metal phosphide nanoparticles, which have to be added to the support in a second step. LEED, STM, XPS, and DFT studies have shown that the surfaces of Ni2P reconstruct to P-rich surfaces. The investigation of metal phosphides as catalysts for hydrotreating reactions continues to be a topic of considerable research with recent advances realized in using bimetallic and noble metal phosphides to achieve high activities and tailored selectivities. Finally, hydrodeoxygenation catalysis over metal phosphides is a growing area of research given the need to develop catalysts for upgrading biomass to transportation fuels.
Starting Page	1413
Ending Page	1436
Page Count	24
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	142
Issue Number	12
e-ISSN	1572879X
Language	English
Publisher	Springer US
Publisher Date	2012-11-09
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	High temperature reduction Phosphate Low temperature reduction Phosphite Hypophosphite Phosphine Trialkylphosphine LEED Ni2P STM Ni2P Bimetallic phosphides Noble metal phosphides HDS, HDN, HDO Industrial Chemistry/Chemical Engineering Catalysis Organometallic Chemistry Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

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