NDLI: Effect of Chlorine on the Chemisorptive Properties and Ammonia Synthesis Activity of Alumina-Supported Ru Catalysts

Content Provider	Springer Nature Link
Author	Lin, Bingyu Wang, Rong Lin, Jianxin Ni, Jun Wei, Kemei
Copyright Year	2011
Abstract	A series of Ru/Al2O3 catalysts were prepared to study the effect of the amount and the origin of residual chlorine on chemisorptive property and the ammonia synthesis activity. The catalysts were characterized by X-ray fluorescence, CO chemisorption, transmission Electron Microscopy, X-ray photoelectron spectroscopy, hydrogen temperature-programmed desorption, hydrogen temperature-programmed reduction. It is found that the presence of chlorine had a limited impact on Ru particle size. Residual chlorine originated from RuCl3 would not influence on Ru 3d5/2 binding energy, but chlorine from HCl solution significantly increased Ru 3d5/2 binding energy. Regardless of their source, the presence of chlorine severely reduced the amount of hydrogen species corresponding to the desorption peak at medium temperature. The inhibition effect of chlorine on hydrogen adsorption was more strong for Ru catalyst with residual chlorine from the RuCl3 precursor. With a similar amount of residual chlorine, the catalysts with chlorine originated from the RuCl3 precursor showed much lower catalytic activity than those prepared by impregnation of HCl. These results suggest that chlorine mainly affects the catalytic properties of alumina supported Ru catalysts for ammonia synthesis by selective site blocking.Chlorine affects on the sites at the metal/support interface for Ru/Al2O3 catalysts, and then hydrogen adsorption and ammonia synthesis both are suppressed.
Starting Page	1557
Ending Page	1568
Page Count	12
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	141
Issue Number	10
e-ISSN	1572879X
Language	English
Publisher	Springer US
Publisher Date	2011-07-29
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Ammonia synthesis Chlorine Alumina supported Ru catalysts Hydrogen temperature-programmed desorption Organometallic Chemistry Catalysis Industrial Chemistry/Chemical Engineering Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Fischer–Tropsch Synthesis: Effect of Reducing Agent for Aqueous-Phase Synthesis Over Ru Nanoparticle and Supported Ru Catalysts

On the Temperature Programmed Desorption of Hydrogen from Polycrystalline Copper

Efficient La–Ba–MgO Supported Ru Catalysts for Ammonia Synthesis

Aqueous-Phase Fischer–Tropsch Synthesis: Effect of Reaction Temperature on Ruthenium Nanoparticle Catalyst and Comparison with Supported Ru and Co Catalysts

Modeling of Temperature-Programmed Desorption (TPD) Flow Experiments from Cu/ZnO/Al2O3 Catalysts

A Monte Carlo study of temperature‐programmed desorption from supported‐metal catalysts

The Temperature-Programmed Desorption of Oxygen from an Alumina-Supported Silver Catalyst

Physicochemical Characterization and H2-TPD Study of Alumina Supported Ruthenium Catalysts

Effect of Nitric Acid Treatment on Carbon Nanotubes (CNTs)-Cordierite Monoliths Supported Ruthenium Catalysts for Ammonia Synthesis

Effect of Chlorine on the Chemisorptive Properties and Ammonia Synthesis Activity of Alumina-Supported Ru Catalysts

Similar Documents

Fischer–Tropsch Synthesis: Effect of Reducing Agent for Aqueous-Phase Synthesis Over Ru Nanoparticle and Supported Ru Catalysts

On the Temperature Programmed Desorption of Hydrogen from Polycrystalline Copper

Efficient La–Ba–MgO Supported Ru Catalysts for Ammonia Synthesis

Aqueous-Phase Fischer–Tropsch Synthesis: Effect of Reaction Temperature on Ruthenium Nanoparticle Catalyst and Comparison with Supported Ru and Co Catalysts

Modeling of Temperature-Programmed Desorption (TPD) Flow Experiments from Cu/ZnO/Al2O3 Catalysts

A Monte Carlo study of temperature‐programmed desorption from supported‐metal catalysts

The Temperature-Programmed Desorption of Oxygen from an Alumina-Supported Silver Catalyst

Physicochemical Characterization and H2-TPD Study of Alumina Supported Ruthenium Catalysts

Effect of Nitric Acid Treatment on Carbon Nanotubes (CNTs)-Cordierite Monoliths Supported Ruthenium Catalysts for Ammonia Synthesis

Effect of Chlorine on the Chemisorptive Properties and Ammonia Synthesis Activity of Alumina-Supported Ru Catalysts