NDLI: Lanthanum and Cesium-Loaded SBA-15 Catalysts for MMA Synthesis by Aldol Condensation of Methyl Propionate and Formaldehyde

Content Provider	Springer Nature Link
Author	Wang, Yanan Yan, Ruiyi Lv, Zhaopo Wang, Hui Wang, Lei Li, Zengxi Zhang, Suojiang
Copyright Year	2016
Abstract	Aldol condensation of methyl propionate (MP) and formaldehyde (FA) is a green and sustainable route to synthesize methyl methacrylate (MMA). In this work, lanthanum and cesium-loaded SBA-15 acid–base bifunctional catalysts for aldol condensation have been prepared by wetness impregnation method to maximize the yield of MMA. With the investigation of the relationship between the properties of catalysts and the catalytic performance, the appropriate acid–base sites for this reaction were provided. The results showed that La existed as LaONO3 on the catalysts and could constitute additional Lewis acid sites on the catalysts. The Cs-0.1La/SBA-15 (with La content of 0.1 %) exhibited higher catalytic activity than the other La-containing catalysts because of the higher density of medium base sites and medium acid sites. The catalysts calcined at 450 °C performed well on this reaction due to the formation of medium base sites on the catalysts as well as the big surface area around 400 m2/g and uniform pore size at 6 nm. When the MP/FA molar ratio was 1/1, the conversion of MP was 29.2 % and the selectivity of MMA could reach 90.4 %.
Starting Page	1808
Ending Page	1818
Page Count	11
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	146
Issue Number	9
e-ISSN	1572879X
Language	English
Publisher	Springer US
Publisher Date	2016-07-19
Publisher Place	New York
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Lanthanum-loaded Aldol condensation Acid and base properties Catalysis Industrial Chemistry/Chemical Engineering Organometallic Chemistry Physical Chemistry
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

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