NDLI: Peroxyacetic Acid Oxidation of Olefins and Alkanes Catalyzed by a Dinuclear Manganese(IV) Complex with 1,4,7-trimethyl-1,4,7-triazacyclononane

Content Provider	Springer Nature Link
Author	Mandelli, Dalmo Kozlov, Yuriy N. Golfeto, Camilla C. Shul’pin, Georgiy B.
Copyright Year	2007
Abstract	Natural terpenes, (−)-limonene and (+)-carvone, can be epoxidized by peroxyacetic acid (PAA) at room temperature if a dinuclear manganese(IV) complex with 1,4,7-trimethyl-1,4,7-triazacyclononane (L), [Mn2L2O3] [PF6]2, is used as a catalyst. The total yield of the epoxides based on the consumed olefins are 97 and 95%, respectively. A kinetic study of the dec-1-ene and cyclohexane oxygenations including the investigation of their simultaneous competitive oxidation was carried out. The olefin epoxidation rate does not depend on dec-1-ene concentration and the dec-1-ene concentration does not affect the rate of cyclohexane oxidation. The cyclohexane oxidation rate is proportional to the alkane concentration. The kinetic analysis led to the conclusion that two species X 1 and X 2 are generated in the system, and there is no their mutual interconversion. The rate equation for the dec-1-ene epoxidation was proposed: W = k +1[cat][PAA], where cat is the initial manganese complex or its derivative, and the constant was determined: k +1 = 3.5 mol−1 dm3 s−1. Species X 1 is apparently an effectively epoxidizing manganese peroxo derivative whereas species X 2 is an alkane hydroxylating manganese oxo complex.
Starting Page	22
Ending Page	29
Page Count	8
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	118
Issue Number	1-2
e-ISSN	1572879X
Language	English
Publisher	Springer US
Publisher Date	2007-07-17
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Alkanes Alkyl hydroperoxides Carvone Epoxidation Homogeneous catalysis Limonene Manganese complexes Olefins Oxidation Peroxyacetic acid Terpenes Pharmacy Industrial Chemistry/Chemical Engineering Physical Chemistry Catalysis
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

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