NDLI: Selective Oxidation of Benzyl Alcohol Over Copper Phthalocyanine Immobilized on MCM-41

Content Provider	Springer Nature Link
Author	Hamza, A. Srinivas, D.
Copyright Year	2008
Abstract	Copper phthalocyanine (CuPc) complexes immobilized on “neat” and Ti4+ and Al3+ containing MCM-41 mimic the functionality of metalloenzymes. These novel materials catalyze the oxidation of benzyl alcohol to selectively benzaldehyde at moderate temperatures using peroxides and molecular oxygen as oxidant. Electron paramagnetic resonance and X-ray photoelectron spectroscopic studies revealed that the acidity of the support (MCM-41) influences the electronic structure of the immobilized CuPc. On acidic supports a part of copper in CuPc got reduced from a “formal” +2 to +1 oxidation state. This reduction of copper in its oxidation state on different supports decreased in the order: Al-MCM-41 (Brönsted and strong Lewis acid sites) > MCM-41 (silanol sites) > Ti-MCM-41 (weak Lewis acid sites). A linear variation in catalytic activity with the concentration of Cu1+ ions in different catalyst samples was observed. The study reveals that by suitably modifying the acidic properties of the support one can, in principle, fine-tune the electronic and catalytic properties of the active oxidation sites.
Starting Page	434
Ending Page	442
Page Count	9
File Format	PDF
ISSN	1011372X
Journal	Catalysis Letters
Volume Number	128
Issue Number	3-4
e-ISSN	1572879X
Language	English
Publisher	Springer US
Publisher Date	2008-11-22
Publisher Place	Boston
Access Restriction	One Nation One Subscription (ONOS)
Subject Keyword	Selective oxidation of benzyl alcohol Copper phthalocyanine MCM-41 EPR UV–visible spectroscopy Pharmacy Industrial Chemistry/Chemical Engineering Physical Chemistry Catalysis
Content Type	Text
Resource Type	Article
Subject	Chemistry Catalysis

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in

Surface-modified Improvement in Catalytic Performance of Cr(salen) Complexes Immobilized on MCM-41 in Solvent-Free Selective Oxidation of Benzyl Alcohol

Environmental Benign Oxidation of Benzyl Alcohol Catalyzed by Sulphonato-Salphen–Chromium(III) Complexes Immobilized on MCM-41

Selective Oxidation of 4-Tert-butyltoluene to 4-Tert-butylbenzaldehyde Over Co/MCM-41

Liquid Phase Oxidation of Cyclohexene Over Selenite Doped MCM-41

Catalytic Oxidation of Alkylaromatics over Mesoporous (Cr)MCM-41

Bis(8-quinolinolato)copper(II) immobilized onto amino-modified SBA-15 for the selective oxidation of benzyl alcohol

Radius of Curvature Effect on the Selective Oxidation of Cyclohexene Over Highly Ordered V-MCM-41

Sunlight-Assisted Photocatalytic Oxidation of Methane over Uranyl-Anchored MCM-41

Characteristics of the Photocatalytic Oxidation of Methane into Methanol on V-Containing MCM-41 Catalysts

Selective Oxidation of Benzyl Alcohol Over Copper Phthalocyanine Immobilized on MCM-41

Similar Documents

Surface-modified Improvement in Catalytic Performance of Cr(salen) Complexes Immobilized on MCM-41 in Solvent-Free Selective Oxidation of Benzyl Alcohol

Environmental Benign Oxidation of Benzyl Alcohol Catalyzed by Sulphonato-Salphen–Chromium(III) Complexes Immobilized on MCM-41

Selective Oxidation of 4-Tert-butyltoluene to 4-Tert-butylbenzaldehyde Over Co/MCM-41

Liquid Phase Oxidation of Cyclohexene Over Selenite Doped MCM-41

Catalytic Oxidation of Alkylaromatics over Mesoporous (Cr)MCM-41

Bis(8-quinolinolato)copper(II) immobilized onto amino-modified SBA-15 for the selective oxidation of benzyl alcohol

Radius of Curvature Effect on the Selective Oxidation of Cyclohexene Over Highly Ordered V-MCM-41

Sunlight-Assisted Photocatalytic Oxidation of Methane over Uranyl-Anchored MCM-41

Characteristics of the Photocatalytic Oxidation of Methane into Methanol on V-Containing MCM-41 Catalysts

Selective Oxidation of Benzyl Alcohol Over Copper Phthalocyanine Immobilized on MCM-41